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Small-Molecule N-Heterocyclic-Carbene-Containing Olefin-Metathesis Catalysts for Use in Water

Authors

  • Jason P. Jordan,

    1. Arnold and Mabel Beckman Laboratory of Chemical Synthesis, Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, CA 91125, USA, Fax: (+1) 626-564-9297
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  • Robert H. Grubbs Prof.

    1. Arnold and Mabel Beckman Laboratory of Chemical Synthesis, Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, CA 91125, USA, Fax: (+1) 626-564-9297
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  • We thank Soon H. Hong for the generous donation of substrates 23 and 25 and for helpful discussions, and Dr. Mona Shahgholi for mass spectroscopic analysis. The National Institutes of Health (5R01M068647) is acknowledged for funding.

Abstract

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Metathese in Wasser: Zwei gut definierte Olefinmetathesekatalysatoren (1 und 2) werden vorgestellt. Sie sind zwar nicht ausreichend stabil für die meisten Kreuzmetathesereaktionen in Wasser, vermitteln aber sehr erfolgreich Ringöffnungsmetathesepolymerisationen und Ringschlussmetathesereaktionen.

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