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A One-Pot Synthesis of Primary Amides from Aldoximes or Aldehydes in Water in the Presence of a Supported Rhodium Catalyst

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  • This work was supported by the Core Research for Evolutional Science and Technology (CREST) program of the Japan Science and Technology Agency (JST) and a Grant-in-Aid for Scientific Research from the Ministry of Education, Culture, Science, Sports and Technology of Japan. We are grateful to Ms. M. Kotani (JST) for her help with the experimental work.

Abstract

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Dehydratisierung und Rehydratisierung in Wasser: Mit dem Rhodiumhydroxid-Trägerkatalysator Rh(OH)x/Al2O3 gelingt die effiziente Synthese von primären Amiden aus Aldoximen und Aldehyden in Wasser ohne Verwendung problematischer organischer Lösungsmittel (siehe Schema).

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