Palladium Nanoparticles Supported on Polyaniline Nanofibers as a Semi-Heterogeneous Catalyst in Water

Authors

  • Benjamin J. Gallon,

    1. Department of Chemistry and Biochemistry, University of California, Los Angeles, 607 Charles E. Young Dr. East, Los Angeles, CA 90095, USA, Fax: (+1) 310-206-4038
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  • Robert W. Kojima,

    1. Department of Chemistry and Biochemistry, University of California, Los Angeles, 607 Charles E. Young Dr. East, Los Angeles, CA 90095, USA, Fax: (+1) 310-206-4038
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  • Richard B. Kaner Prof.,

    1. Department of Chemistry and Biochemistry, University of California, Los Angeles, 607 Charles E. Young Dr. East, Los Angeles, CA 90095, USA, Fax: (+1) 310-206-4038
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  • Paula L. Diaconescu Prof.

    1. Department of Chemistry and Biochemistry, University of California, Los Angeles, 607 Charles E. Young Dr. East, Los Angeles, CA 90095, USA, Fax: (+1) 310-206-4038
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  • This work was supported by NSF (grant DMR 0507294 to R.B.K.) and UCLA. We thank Erin Broderick for help with some reaction procedures.

Abstract

original image

Ein Tandemkatalysator für die Suzuki-Kupplung aktivierter oder desaktivierter Arylchloride mit Arylboronsäuren in Wasser und für die Phenolsynthese ausgehend von Arylchloriden in Wasser/Dioxan (1:1) entstand durch das Aufbringen von Palladiumnanopartikeln auf Polyanilin-Nanofasern (PANI; siehe TEM-Bild). So wurde 2-Phenylphenol aus 1,2-Dichlorbenzol synthetisiert (siehe Gleichung).

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