Zuschrift

Unprecedented Tetranuclear Complexes with 20-Electron NiII Centers: The Role of Pressure and Temperature on Their Solid-State and Solution Fragmentation†

  1. Anthony Kermagoret1,
  2. Roberto Pattacini Dr.1,
  3. Patricia Chavez Vasquez1,
  4. Guillaume Rogez Dr.2,
  5. Richard Welter Prof.3,
  6. Pierre Braunstein Dr.1

Article first published online: 16 JUL 2007

DOI: 10.1002/ange.200701483

Issue

Angewandte Chemie

Angewandte Chemie

Volume 119, Issue 34, pages 6558–6561, August 27, 2007

Additional Information

How to Cite

Kermagoret, A., Pattacini, R., Chavez Vasquez, P., Rogez, G., Welter, R. and Braunstein, P. (2007), Unprecedented Tetranuclear Complexes with 20-Electron NiII Centers: The Role of Pressure and Temperature on Their Solid-State and Solution Fragmentation. Angew. Chem., 119: 6558–6561. doi: 10.1002/ange.200701483

Author Information

  1. 1

    Laboratoire de Chimie de Coordination, Institut de Chimie, UMR 7177 CNRS, Université Louis Pasteur, 4 rue Blaise Pascal, 67070 Strasbourg Cedex, France, Fax: (+33) 390-241-322 http://www-chimie.u-strasbg.fr/∼lcc/

  2. 2

    Groupe des Matériaux Inorganiques, IPCMS, UMR 7504 CNRS, 23, rue du Loess, B.P. 43, 67034 Strasbourg Cedex 2, France

  3. 3

    DECOMET, Institut de Chimie, UMR 7177 CNRS, Université Louis Pasteur, 4 rue Blaise Pascal, 67070 Strasbourg Cedex, France

  1. †

    This work was supported by the Centre National de la Recherche Scientifique and the Ministère de l'Enseignement Supérieur et de la Recherche. We thank Dr. D. Mandon for assistance with the variable-temperature UV/Vis measurements.

Publication History

  1. Issue published online: 20 AUG 2007
  2. Article first published online: 16 JUL 2007
  3. Manuscript Revised: 7 JUN 2007
  4. Manuscript Received: 5 APR 2007

Funded by

  • Centre National de la Recherche Scientifique
  • Ministère de l'Enseignement Supérieur et de la Recherche

SEARCH

SEARCH BY CITATION

ARTICLE TOOLS

View Full Article with Supporting Information (HTML) Get PDF (390K)

Keywords:

  • Isomerisierungen;
  • Magnetische Eigenschaften;
  • Mehrkernkomplexe;
  • N,P-Liganden;
  • Nickel
Thumbnail image of graphical abstract

Unter Druck! Die Komplexe [{NiCl2(PN)}4] (PN=2-Diphenylphosphinomethyl-2-oxazolin oder -2-thiazolin; siehe Bild; Ni grün, Cl rosa, P orange, S gelb, N blau, C grau) haben einen neuartigen zentrosymmetrischen Ni4Cl8-Kern mit 20-Elektronen-Metallzentren und wandeln sich unter Druck in die einkernigen quadratisch-planaren 16-Elektronenkomplexe [NiCl2(PN)] um, die in Lösung mit dem jeweiligen Tetramer im Gleichgewicht stehen.

View Full Article with Supporting Information (HTML) Get PDF (390K)