We thank the National Institutes of Health (NIH) for support (GM-058160). We thank Amgen, Merck, and Boehringer Ingelheim for additional unrestricted funds. We are grateful to BASF for a gift of PdCl2. M.R.B. thanks the NIH for a postdoctoral fellowship (GM-F32-75685). T.E.B. was supported, in part, by an ACS Organic Division Award (Novartis). The Bruker Advance 400 MHz NMR spectrometer used in this study was purchased with funding from the NIH (GM 1S10RR13886-01).
Electronic Effects on the Selectivity of Pd-Catalyzed CN Bond-Forming Reactions Using Biarylphosphine Ligands: The Competitive Roles of Amine Binding and Acidity†
Article first published online: 6 AUG 2007
Copyright © 2007 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
Volume 119, Issue 38, pages 7370–7373, September 24, 2007
How to Cite
Biscoe, Mark R., Barder, Timothy E. and Buchwald, Stephen L. (2007), Electronic Effects on the Selectivity of Pd-Catalyzed CN Bond-Forming Reactions Using Biarylphosphine Ligands: The Competitive Roles of Amine Binding and Acidity. Angew. Chem., 119: 7370–7373. doi: 10.1002/ange.200702122
- Issue published online: 17 SEP 2007
- Article first published online: 6 AUG 2007
- Manuscript Received: 15 MAY 2007
- National Institutes of Health (NIH). Grant Number: GM-058160
- NIH. Grant Number: GM-F32-75685
- NIH. Grant Number: GM 1S10RR13886-01
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