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Two-Step Adsorption/Desorption on a Jungle-Gym-Type Porous Coordination Polymer

Authors

  • Kazuhiro Uemura Dr.,

    1. Environmental Science and Engineering, Graduate School of Science and Engineering, Yamaguchi University, Tokiwadai 2-16-1, Ube-shi, Yamaguchi 755-8611, Japan, Fax: (+81) 836-85-9601
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  • Yukari Yamasaki,

    1. Environmental Science and Engineering, Graduate School of Science and Engineering, Yamaguchi University, Tokiwadai 2-16-1, Ube-shi, Yamaguchi 755-8611, Japan, Fax: (+81) 836-85-9601
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  • Yuki Komagawa,

    1. Environmental Science and Engineering, Graduate School of Science and Engineering, Yamaguchi University, Tokiwadai 2-16-1, Ube-shi, Yamaguchi 755-8611, Japan, Fax: (+81) 836-85-9601
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  • Kazuhiro Tanaka Dr.,

    1. Environmental Science and Engineering, Graduate School of Science and Engineering, Yamaguchi University, Tokiwadai 2-16-1, Ube-shi, Yamaguchi 755-8611, Japan, Fax: (+81) 836-85-9601
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  • Hidetoshi Kita Prof. Dr.

    1. Environmental Science and Engineering, Graduate School of Science and Engineering, Yamaguchi University, Tokiwadai 2-16-1, Ube-shi, Yamaguchi 755-8611, Japan, Fax: (+81) 836-85-9601
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  • This work was supported by the Grants-in-Aid for Scientific Research (Young Scientist (B) No. 19750048) and the Kao Foundation for Arts and Sciences.

Abstract

original image

Flexible Gerüste: Einzigartige zweistufige Isothermen wurden bei der Adsorption/Desorption von Propan-2-ol an [{Zn2(1,4-Benzoldicarboxylat)2(1,4-Diazabicyclo[2.2.2]octan)}n] mit hydrophoben Hohlräumen beobachtet. Die Isothermen wurden durch thermische Analyse und Röntgenbeugung am Einkristall charakterisiert (siehe Bild).

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