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A Heterobimetallic Pd/La/Schiff Base Complex for anti-Selective Catalytic Asymmetric Nitroaldol Reactions and Applications to Short Syntheses of β-Adrenoceptor Agonists

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  • This work was partially supported by a Grant-in-Aid for Specially Promoted Research from MEXT, and a Grant-in-Aid for Encouragements for Young Scientists (B) (Y.S.), from JSPS, and Mitsubishi Chemical Corporation Fund (S.M.), and Toray Co Ltd.

Abstract

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Passgenau für zwei Metalle: Die Kombination aus Pd und La in einem Schiff-Base-Liganden führt zu einer anti-selektiven katalytischen asymmetrischen Nitroaldolreaktion (siehe Schema). Mithilfe des Heterodimetallkatalysators gelingen kurze Synthesen von β-Adrenozeptor-Agonisten.

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