Zuschrift

An All-Inorganic, Stable, and Highly Active Tetraruthenium Homogeneous Catalyst for Water Oxidation†

  1. Yurii V. Geletii Dr.2,
  2. Bogdan Botar Dr.1,
  3. Paul Kögerler Dr.1,
  4. Daniel A. Hillesheim2,
  5. Djamaladdin G. Musaev Dir. Dr.3,
  6. Craig L. Hill Prof. Dr.2

Article first published online: 19 MAR 2008

DOI: 10.1002/ange.200705652

Issue

Angewandte Chemie

Angewandte Chemie

Volume 120, Issue 21, pages 3960–3963, May 13, 2008

Additional Information

How to Cite

Geletii, Y., Botar, B., Kögerler, P., Hillesheim, D., Musaev, D. and Hill, C. (2008), An All-Inorganic, Stable, and Highly Active Tetraruthenium Homogeneous Catalyst for Water Oxidation. Angewandte Chemie, 120: 3960–3963. doi: 10.1002/ange.200705652

Author Information

  1. 1

    Institut für Festkörperforschung, Forschungszentrum Jülich GmbH, 52425 Jülich, Germany, Fax: (+49) 2461-612-620

  2. 2

    Department of Chemistry, Emory University, 1515 Dickey Drive, Atlanta, GA 30322, USA, Fax: (+1) 404-727-6076

  3. 3

    Cherry L. Emerson Center for Scientific Computation, Emory University, 1515 Dickey Drive, Atlanta, GA 30322, USA

  1. †

    This work was supported by the following grants to C.L.H. & D.G.M.: U.S. Department of Energy (DE-FG02-03ER15461 and DE-FG02-06ER06-15). We thank Ken Hardcastle and Rui Cao for X-ray crystallographic efforts.

Publication History

  1. Issue published online: 6 MAY 2008
  2. Article first published online: 19 MAR 2008
  3. Manuscript Revised: 14 FEB 2008
  4. Manuscript Received: 10 DEC 2007

Funded by

  • U.S. Department of Energy. Grant Numbers: DE-FG02-03ER15461, DE-FG02-06ER06-15

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Keywords:

  • Disauerstoff;
  • Elektrochemie;
  • Homogene Katalyse;
  • Oxidationen;
  • Polyoxometallate

Graphical Abstract

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Oxidation ohne Organik: Ein Tetraruthenium-Polyoxometallat-Hybrid (siehe Bild; Ru blau, O rot, Si gelb, W schwarz) katalysiert die schnelle Oxidation von H2O zu O2 bei Raumtemperatur. Der unter den Reaktionsbedingungen stabile Komplex wurde unter anderem kristallographisch und cyclovoltammetrisch charakterisiert.

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