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Designed Synthesis of POM–Organic Frameworks from {Ni6PW9} Building Blocks under Hydrothermal Conditions

Authors

  • Shou-Tian Zheng,

    1. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China, Fax: (+86) 591-8371-0051
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  • Jie Zhang Prof. Dr.,

    1. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China, Fax: (+86) 591-8371-0051
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  • Guo-Yu Yang Prof. Dr.

    1. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China, Fax: (+86) 591-8371-0051
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  • This work was supported by the National Natural Science Fund for Distinguished Young Scholars of China (no. 20725101), the 973 Program (no. 2006CB932904), the NNSF of China (no. 20473093), the NSF of Fujian Province (no. E0510030), and the Knowledge Innovation Program of CAS (no. KJCX2.YW.H01). POM=polyoxometalate.

Abstract

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Die direkte Kombination von {Ni6PW9}-Baugruppen mit starren Carboxylatbrücken unter Hydrothermalbedingungen führt zu Polyoxometallat-organischen Netzwerken (POMOFs) mit 1D-, 2D- und 3D-Strukturen auf der Grundlage von Monomeren, Dimeren oder helikalen Ketten (siehe Bild einer 3D-Struktur; WO6 rot, NiO6 grün, PO4 gelb, 1,2,4-Benzoltricarboxylat gold).

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