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A Four-Shell, Nesting Doll-like 3d–4f Cluster Containing 108 Metal Ions

Authors

  • Xiang-Jian Kong,

    1. State Key Laboratory of Physical Chemistry of Solid Surface and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China, Fax: (+86) 592-218-3047
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  • Yan-Ping Ren,

    1. State Key Laboratory of Physical Chemistry of Solid Surface and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China, Fax: (+86) 592-218-3047
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  • Wen-Xian Chen,

    1. State Key Laboratory of Physical Chemistry of Solid Surface and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China, Fax: (+86) 592-218-3047
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  • La-Sheng Long Prof. Dr.,

    1. State Key Laboratory of Physical Chemistry of Solid Surface and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China, Fax: (+86) 592-218-3047
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  • Zhiping Zheng Prof.,

    1. State Key Laboratory of Physical Chemistry of Solid Surface and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China, Fax: (+86) 592-218-3047
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  • Rong-Bin Huang Prof. Dr.,

    1. State Key Laboratory of Physical Chemistry of Solid Surface and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China, Fax: (+86) 592-218-3047
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  • Lan-Sun Zheng Prof. Dr.

    1. State Key Laboratory of Physical Chemistry of Solid Surface and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China, Fax: (+86) 592-218-3047
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  • We thank the NNSFC (grant nos. 20471050, 20531050, and 20423002), the 973 project (grant no. 2007CB815304) from MSTC, and the U.S. NSF (CAREER CHE-0238790) for financial support.

Abstract

original image

Metallionen-Matrjoschka: Ein 108-kerniger Heterometallcluster mit außergewöhnlicher konzentrischer Vier-Schalen-Struktur (siehe Bild) und antiferromagnetischer Kopplung wird beschrieben.

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