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Aerobic Oxidative Kinetic Resolution of Racemic Secondary Alcohols with Chiral Bifunctional Amido Complexes

Authors

  • Sachiko Arita,

    1. Department of Applied Chemistry, Graduate School of Science and Engineering, Tokyo Institute of Technology, 2-12-1 O-okayama, Meguro-ku, Tokyo 152-8552, Japan, Fax: (+81) 3-5734-2637
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  • Takashi Koike Dr.,

    1. Department of Applied Chemistry, Graduate School of Science and Engineering, Tokyo Institute of Technology, 2-12-1 O-okayama, Meguro-ku, Tokyo 152-8552, Japan, Fax: (+81) 3-5734-2637
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  • Yoshihito Kayaki Dr.,

    1. Department of Applied Chemistry, Graduate School of Science and Engineering, Tokyo Institute of Technology, 2-12-1 O-okayama, Meguro-ku, Tokyo 152-8552, Japan, Fax: (+81) 3-5734-2637
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  • Takao Ikariya Prof. Dr.

    1. Department of Applied Chemistry, Graduate School of Science and Engineering, Tokyo Institute of Technology, 2-12-1 O-okayama, Meguro-ku, Tokyo 152-8552, Japan, Fax: (+81) 3-5734-2637
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  • This work was financially supported by a Grant-in-Aid from the Ministry of Education, Culture, Sports, Science and Technology (Japan) (No. 18065007) and partially supported by The 21st Century COE and G-COE Programs.

Abstract

original image

Frische Luft: Die kinetische Racematspaltung sekundärer Alkohole durch Luftoxidation mit chiralen difunktionellen Iridium-, Rhodium- und Rutheniumkatalysatoren ergibt die chiralen Alkohole glatt und mit bis zu 99 % ee. Unter den milden Bedingungen erweist sich O2 als ausgezeichneter Wasserstoffakzeptor.

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