Zuschrift

N-Confused and N-Fused meso-Aryl Sapphyrins†

  1. Iti Gupta Dr.1,2,
  2. Alagar Srinivasan Dr.1,
  3. Tatsuki Morimoto Dr.1,
  4. Motoki Toganoh Dr.1,
  5. Hiroyuki Furuta Prof. Dr.1

Article first published online: 5 MAY 2008

DOI: 10.1002/ange.200705984

Issue

Angewandte Chemie

Angewandte Chemie

Volume 120, Issue 24, pages 4639–4643, June 2, 2008

Additional Information

How to Cite

Gupta, I., Srinivasan, A., Morimoto, T., Toganoh, M. and Furuta, H. (2008), N-Confused and N-Fused meso-Aryl Sapphyrins. Angew. Chem., 120: 4639–4643. doi: 10.1002/ange.200705984

Author Information

  1. 1

    Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University, Fukuoka 819-0395, Japan, Fax: (+81) 92-802-2865

  2. 2

    Current address: BITS-Pilani, Goa Campus, Near NH-17B, Bye Pass Road Zuarinagar, Goa 403 726, India

  1. †

    I.G. thanks the JST and JSPS for fellowships, and H.F. thanks PRESTO, JST, and a Grant-in-Aid for the Global COE Program, “Science for Future Molecular Systems” from the MEXT (Japan) for financial support.

Publication History

  1. Issue published online: 27 MAY 2008
  2. Article first published online: 5 MAY 2008
  3. Manuscript Received: 30 DEC 2007

Funded by

  • PRESTO
  • JST
  • MEXT (Japan)

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Keywords:

  • Kondensierte Ringe;
  • Porphyrinoide;
  • Rhenium;
  • Sapphyrine
Thumbnail image of graphical abstract

Ringe in Aufruhr: Der Einschub eines verdrehten Pyrrolrings destabilisiert ein Mesoarylsapphyrin-Gerüst und erzwingt einen Ringschluss. Die anschließende Metallierung mit Rhenium resultiert in einer weiteren Anellierung unter Bildung eines Sapphyrins mit fünf anellierten Ringen (siehe Schema).

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