Innentitelbild: Amplified Chiral Transformation through Helical Assembly (Angew. Chem. 34/2007)

Authors

  • Kunihiko Toyofuku,

    1. Department of Chemistry and Biotechnology, School of Engineering and Center for NanoBio Integration, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan, Fax: (+81) 3-5841-7310
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  • Md. Akhtarul Alam Dr.,

    1. Department of Chemistry and Biotechnology, School of Engineering and Center for NanoBio Integration, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan, Fax: (+81) 3-5841-7310
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  • Akihiko Tsuda Dr.,

    1. Department of Chemistry and Biotechnology, School of Engineering and Center for NanoBio Integration, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan, Fax: (+81) 3-5841-7310
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  • Norifumi Fujita Dr.,

    1. Department of Chemistry and Biotechnology, School of Engineering and Center for NanoBio Integration, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan, Fax: (+81) 3-5841-7310
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  • Shigeru Sakamoto Dr.,

    1. Laboratory of Analytical Chemistry, Department of Pharmaceutical Technology, Faculty of Pharmaceutical Sciences at Kagawa Campus, Tokushima Bunri University, Shido, Sanuki-city 769-2193, Japan
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    • Responsible for cold-spray-ionization mass spectrometry.

  • Kentaro Yamaguchi Prof. Dr.,

    1. Laboratory of Analytical Chemistry, Department of Pharmaceutical Technology, Faculty of Pharmaceutical Sciences at Kagawa Campus, Tokushima Bunri University, Shido, Sanuki-city 769-2193, Japan
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    • Responsible for cold-spray-ionization mass spectrometry.

  • Takuzo Aida Prof. Dr.

    1. Department of Chemistry and Biotechnology, School of Engineering and Center for NanoBio Integration, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan, Fax: (+81) 3-5841-7310
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Abstract

original image

„Chiralitätsverstärkung“ durch Umwandlung eines Substrats in eine helicale polymere Vorstufe, in der die Händigkeit durch das “Mehrheitsprinzip” bestimmt wird, schildern T. Aida et al. in der Zuschrift auf S. 6596 ff. Die grundlegende Strategie, die durch die asymmetrische Umwandlung eines D2-symmetrischen sattelförmigen Porphyrins mit Chiralitätsgedächtnis demonstriert wird, könnte ein neues Grundprinzip für die allgemeine asymmetrische Synthese bilden.

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