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The Synthesis and Isolation of a Metal-Substituted Bis-silene

Authors

  • Dmitry Bravo-Zhivotovskii Dr.,

    1. Schulich Faculty of Chemistry and The Lise Meitner-Minerva Center for Computational Quantum Chemistry, Technion-Israel Institute of Technology, Haifa 32000, Israel, Fax: (+972) 4-829-4601
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  • Roman Dobrovetsky,

    1. Schulich Faculty of Chemistry and The Lise Meitner-Minerva Center for Computational Quantum Chemistry, Technion-Israel Institute of Technology, Haifa 32000, Israel, Fax: (+972) 4-829-4601
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  • Dmitry Nemirovsky,

    1. Schulich Faculty of Chemistry and The Lise Meitner-Minerva Center for Computational Quantum Chemistry, Technion-Israel Institute of Technology, Haifa 32000, Israel, Fax: (+972) 4-829-4601
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  • Victoria Molev,

    1. Schulich Faculty of Chemistry and The Lise Meitner-Minerva Center for Computational Quantum Chemistry, Technion-Israel Institute of Technology, Haifa 32000, Israel, Fax: (+972) 4-829-4601
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  • Michael Bendikov Dr.,

    1. Department of Organic Chemistry, Weizmann Institute of Science, Rehovot 76100, Israel
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  • Gregory Molev,

    1. Schulich Faculty of Chemistry and The Lise Meitner-Minerva Center for Computational Quantum Chemistry, Technion-Israel Institute of Technology, Haifa 32000, Israel, Fax: (+972) 4-829-4601
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  • Mark Botoshansky Dr.,

    1. Schulich Faculty of Chemistry and The Lise Meitner-Minerva Center for Computational Quantum Chemistry, Technion-Israel Institute of Technology, Haifa 32000, Israel, Fax: (+972) 4-829-4601
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  • Yitzhak Apeloig Prof.

    1. Schulich Faculty of Chemistry and The Lise Meitner-Minerva Center for Computational Quantum Chemistry, Technion-Israel Institute of Technology, Haifa 32000, Israel, Fax: (+972) 4-829-4601
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  • This research was supported by the Israel Science Foundation, the Fund for the Promotion of Research at the Technion, and the Minerva Foundation in Munich. D.B.-Z. and Mark B. are grateful to the Ministry of Immigrant Absorption (Israel) for a Kamea scholarship.

Abstract

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Bis(s)-chen Si-Chemie: Bis(lithiosilyl)quecksilber mit iPr3Si-Substituenten reagiert mit zwei Äquivalenten 1-Adamantoylchlorid durch thermische Brook-Umlagerung zum ersten metallsubstituierten Bis(silen). Bis(lithiosilyl)quecksilber mit den kleineren tBuMe2Si-Substituenten dagegen ergab ein Bis(acylsilyl)quecksilber, das sich nicht in das Bis(silen) umlagerte. Der Einfluss sterischer Faktoren auf die Brook-Umlagerung wurde rechnerisch untersucht.

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