Zuschrift

Ruthenium Porphyrin-Catalyzed Aerobic Oxidation of Terminal Aryl Alkenes to Aldehydes by a Tandem Epoxidation–Isomerization Pathway†

  1. Gaoxi Jiang1,
  2. Jian Chen Dr.1,
  3. Hung-Yat Thu Dr.2,
  4. Jie-Sheng Huang Dr.2,
  5. Nianyong Zhu Dr.2,
  6. Chi-Ming Che Prof. Dr.1,2

Article first published online: 24 JUL 2008

DOI: 10.1002/ange.200801500

Issue

Angewandte Chemie

Angewandte Chemie

Volume 120, Issue 35, pages 6740–6744, August 18, 2008

Additional Information

How to Cite

Jiang, G., Chen, J., Thu, H.-Y., Huang, J.-S., Zhu, N. and Che, C.-M. (2008), Ruthenium Porphyrin-Catalyzed Aerobic Oxidation of Terminal Aryl Alkenes to Aldehydes by a Tandem Epoxidation–Isomerization Pathway. Angew. Chem., 120: 6740–6744. doi: 10.1002/ange.200801500

Author Information

  1. 1

    Shanghai-Hong Kong Joint Laboratory in Chemical Synthesis, Shanghai Institute of Organic Chemistry, The Chinese Academy of Sciences, 354 Feng Lin Road, Shanghai 200032 (China)

  2. 2

    Department of Chemistry and Open Laboratory of Chemical Biology of the Institute of Molecular Technology for Drug Discovery and Synthesis, The University of Hong Kong, Pokfulam Road, Hong Kong, Fax: (+852) 28571586

  1. †

    We are thankful for the financial support of The University of Hong Kong (University Development Fund), the University Grants Council of HKSAR (the Area of Excellence Scheme: AoE 10/01P), the Hong Kong Research Grants Council (HKU7009/06P and CityU 2/06C), and CAS-Croucher Funding Scheme for Joint Laboratory. G.J. and J.C. thank the Croucher Foundation of Hong Kong for a postgraduate studentship.

Publication History

  1. Issue published online: 8 AUG 2008
  2. Article first published online: 24 JUL 2008
  3. Manuscript Received: 31 MAR 2008

Funded by

  • The University of Hong Kong
  • University Grants Council of HKSAR. Grant Number: AoE 10/01P
  • Hong Kong Research Grants Council. Grant Numbers: HKU7009/06P, CityU 2/06C
  • CAS-Croucher Funding Scheme for Joint Laboratory
  • Croucher Foundation of Hong Kong

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Keywords:

  • Alkene;
  • Homogene Katalyse;
  • N-Liganden;
  • Oxidationen;
  • Ruthenium
Thumbnail image of graphical abstract

Die katalytische Oxidation von 1-Alkenen zu Aldehyden über eine Epoxidierung-Isomerisierung gelang mit Luft oder Disauerstoff als stöchiometrischem Oxidationsmittel in Gegenwart sperriger RuIV- oder RuVI-Porphyrin-Katalysatoren. Der wiederverwendbare Katalysator [RuVI(tmttp)O2] erreichte Produktausbeuten von 99 % bei Umsatzzahlen bis 1144. tmttp=1,3,5,7-Tetramethyl-2,4,6,8-tetraterphenylporphyrinato-Dianion.

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