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A Surface Coordination Network Based on Substrate-Derived Metal Adatoms with Local Charge Excess†

  1. Greg Pawin1,3,
  2. Kin L. Wong1,2,
  3. Daeho Kim1,3,
  4. Dezheng Sun1,
  5. Ludwig Bartels1,3,
  6. Sampyo Hong4,
  7. Talat S. Rahman4,
  8. Robert Carp3,
  9. Michael Marsella3

Article first published online: 29 AUG 2008

DOI: 10.1002/ange.200802543

Issue

Angewandte Chemie

Angewandte Chemie

Volume 120, Issue 44, pages 8570–8573, October 20, 2008

Additional Information

How to Cite

Pawin, G., Wong, Kin L., Kim, D., Sun, D., Bartels, L., Hong, S., Rahman, Talat S., Carp, R. and Marsella, M. (2008), A Surface Coordination Network Based on Substrate-Derived Metal Adatoms with Local Charge Excess. Angew. Chem., 120: 8570–8573. doi: 10.1002/ange.200802543

Author Information

  1. 1

    University of California-Riverside, Pierce Hall, Riverside, CA 92521 (USA)

  2. 2

    University of California-Los Angeles, 6266-D Boelter Hall, Los Angeles, CA 90095 (USA)

  3. 3

    Department of Chemistry, University of California-Riverside, Riverside, CA 92521 (USA)

  4. 4

    Department of Physics, University of Central Florida, Orlando, FL 32816 (USA)

  1. †

    This work was supported by the US Department of Energy under grants DE-FGO2-03ER15464 (Bartels)/DE-FG02-07ER15842 (Rahman) and the US National Science Foundation 0647152 (Bartels/Marsella). Computational resources were made available by the San Diego Supercomputer Center.

Publication History

  1. Issue published online: 15 OCT 2008
  2. Article first published online: 29 AUG 2008
  3. Manuscript Received: 31 MAY 2008

Funded by

  • US Department of Energy. Grant Numbers: DE-FGO2-03ER15464, DE-FG02-07ER15842
  • US National Science Foundation. Grant Number: 0647152

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Keywords:

  • Dichtefunktionalrechnungen;
  • Koordinationschemie;
  • Oberflächenchemie;
  • Rastersondenverfahren;
  • Strukturaufklärung
Thumbnail image of graphical abstract

Oberflächensafari: 9,10-Anthracendicarbonitril(DCA)-Moleküle auf einer Cu(111)-Oberfläche können durch graduelles Tempern des Substrats titriert werden, wobei zunächst trigonal-planare Cu(DCA)3-Komplexe und dann ein hexagonales Netzwerk (siehe Bild) mit Cu2(DCA)3-Stöchiometrie entstehen. Wegen der Ladungsübertragung vom Substrat bleibt das koordinierte Cu-Adatom elektrisch neutral, obwohl es ungefähr 1/3 Ladung auf jede Cu-N-Bindung überträgt.

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