Template-Directed Assembly of Zeolite-like Metal–Organic Frameworks (ZMOFs): A usf-ZMOF with an Unprecedented Zeolite Topology

Authors

  • Yunling Liu Dr.,

    1. Department of Chemistry, University of South Florida, 4202 East Fowler Avenue (CHE 205), Tampa, FL 33620 (USA), Fax: (+1) 813-974-3203
    2. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012 (P.R. China)
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  • Victor Ch. Kravtsov Dr.,

    1. Department of Chemistry, University of South Florida, 4202 East Fowler Avenue (CHE 205), Tampa, FL 33620 (USA), Fax: (+1) 813-974-3203
    2. Institute of Applied Physics of Academy of Sciences of Moldova, Academiei 5, MD2028 Chisinau (Moldova)
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  • Mohamed Eddaoudi Prof. Dr.

    1. Department of Chemistry, University of South Florida, 4202 East Fowler Avenue (CHE 205), Tampa, FL 33620 (USA), Fax: (+1) 813-974-3203
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  • We gratefully acknowledge the financial support of the National Science Foundation (DMR 0548117) and the Department of Energy DOE-BES (DE0FG02-07ER4670).

Abstract

original image

Zeolith mit Indium: Molekulare Bausteine (MBBs) mit achtfach koordinierten Indiumzentren und 4,5-Imidazoldicarboxylat(Himdc)-Liganden bauen in Gegenwart eines strukturgebenden Agens ein vierfach verknüpftes Zeolith-artiges metall-organisches Netzwerk (ZMOF) mit neuartiger Zeolithtopologie auf (med-Topologie, siehe Bild; In grün, C grau, N blau, O rot; die Netzwerktopologie von usf-ZMOF ist durch grüne Tetraeder veranschaulicht).

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