Harnessing Glycal-Epoxide Rearrangements: The Generation of the AB, EF, and IJ Rings of Adriatoxin


  • We are grateful to the National Institutes of Health, General Medical Sciences (GM56677) for support of this work. C.O.A. acknowledges Pfizer for a graduate fellowship. We would like to thank the support staff at the University of Utah and especially Dr. Charles Mayne (NMR) and Dr. Jim Muller (MS) for their help in obtaining data.


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Die Leiter hoch: Der Aufbau dreier bicyclischer Untereinheiten von Adriatoxin gelang mithilfe von Glycal-Epoxid- und Glycal-Claisen-Umlagerungen sowie C-Glycosid bildenden Reaktionen.