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Heterogeneously Hybridized Porous Coordination Polymer Crystals: Fabrication of Heterometallic Core–Shell Single Crystals with an In-Plane Rotational Epitaxial Relationship

Authors

  • Shuhei Furukawa Dr.,

    1. ERATO Kitagawa Integrated Pores Project (Japan), Kyoto Research Park Bldg #3, Shimogyo-ku, Kyoto 600-8815 (Japan), Fax: (+81) 75-325-3572 http://kip.jst.go.jp
    2. Institute for Integrated Cell-Material Sciences (iCeMS), Kyoto University, Yoshida, Sakyo-ku, Kyoto 606-8501 (Japan)
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  • Kenji Hirai,

    1. Department of Synthetic Chemistry & Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510 (Japan)
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  • Keiji Nakagawa,

    1. Department of Synthetic Chemistry & Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510 (Japan)
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  • Yohei Takashima,

    1. Department of Synthetic Chemistry & Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510 (Japan)
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  • Ryotaro Matsuda Dr.,

    1. ERATO Kitagawa Integrated Pores Project (Japan), Kyoto Research Park Bldg #3, Shimogyo-ku, Kyoto 600-8815 (Japan), Fax: (+81) 75-325-3572 http://kip.jst.go.jp
    2. Institute for Integrated Cell-Material Sciences (iCeMS), Kyoto University, Yoshida, Sakyo-ku, Kyoto 606-8501 (Japan)
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  • Takaaki Tsuruoka Dr.,

    1. ERATO Kitagawa Integrated Pores Project (Japan), Kyoto Research Park Bldg #3, Shimogyo-ku, Kyoto 600-8815 (Japan), Fax: (+81) 75-325-3572 http://kip.jst.go.jp
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  • Mio Kondo Dr.,

    1. Institute for Integrated Cell-Material Sciences (iCeMS), Kyoto University, Yoshida, Sakyo-ku, Kyoto 606-8501 (Japan)
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  • Rie Haruki Dr.,

    1. Research & Utilization Division (Japan), Synchrotron Radiation Research Institute/SPring-8 and CREST, JST, Kouto, Sayo, Hyogo 679-5198 (Japan)
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  • Daisuke Tanaka Dr.,

    1. Department of Synthetic Chemistry & Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510 (Japan)
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  • Hirotoshi Sakamoto,

    1. Department of Synthetic Chemistry & Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510 (Japan)
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  • Satoru Shimomura,

    1. Department of Synthetic Chemistry & Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510 (Japan)
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  • Osami Sakata Dr.,

    1. Research & Utilization Division (Japan), Synchrotron Radiation Research Institute/SPring-8 and CREST, JST, Kouto, Sayo, Hyogo 679-5198 (Japan)
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  • Susumu Kitagawa Prof.

    1. ERATO Kitagawa Integrated Pores Project (Japan), Kyoto Research Park Bldg #3, Shimogyo-ku, Kyoto 600-8815 (Japan), Fax: (+81) 75-325-3572 http://kip.jst.go.jp
    2. Institute for Integrated Cell-Material Sciences (iCeMS), Kyoto University, Yoshida, Sakyo-ku, Kyoto 606-8501 (Japan)
    3. Department of Synthetic Chemistry & Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510 (Japan)
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  • The synchrotron X-ray diffraction experiments were performed at BL13XU in the SPring-8 with the approval of the JASRI (Proposal No. 2007A1825, 2007B1771, and 2008A1574).

Abstract

MOF im MOF: Einkristalle eines porösen Kern-Schale-Koordinationspolymers (PCP) wurden durch epitaxiales Wachstum in Lösung erzeugt. Synchrotron-Röntgenbeugungsmessungen offenbarten die strukturellen Beziehungen zwischen dem Kern- und Schalenkristall: Ein epitaxiales Wachstum in verdrehter Orientierung gleicht die unterschiedlichen Gitterkonstanten aus.

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