Get access

Thallium(I) as a Coordination Site Protection Agent: Preparation of an Isolable Zero-Valent Nickel Tris-Isocyanide

Authors

  • Brian J. Fox,

    1. Department of Chemistry and Biochemistry, University of California, San Diego, 9500 Gilman Drive MC 0358, La Jolla, CA 92193 (USA), Fax: (+1) 858-822-4442
    Search for more papers by this author
  • Matthew D. Millard,

    1. Department of Chemistry and Biochemistry, University of California, San Diego, 9500 Gilman Drive MC 0358, La Jolla, CA 92193 (USA), Fax: (+1) 858-822-4442
    Search for more papers by this author
  • Antonio G. DiPasquale Dr.,

    1. Department of Chemistry and Biochemistry, University of California, San Diego, 9500 Gilman Drive MC 0358, La Jolla, CA 92193 (USA), Fax: (+1) 858-822-4442
    Search for more papers by this author
  • Arnold L. Rheingold Prof. Dr.,

    1. Department of Chemistry and Biochemistry, University of California, San Diego, 9500 Gilman Drive MC 0358, La Jolla, CA 92193 (USA), Fax: (+1) 858-822-4442
    Search for more papers by this author
  • Joshua S. Figueroa Prof. Dr.

    1. Department of Chemistry and Biochemistry, University of California, San Diego, 9500 Gilman Drive MC 0358, La Jolla, CA 92193 (USA), Fax: (+1) 858-822-4442
    Search for more papers by this author

  • We gratefully acknowledge the UCSD Department of Chemistry and Biochemistry and the Camille and Henry Dreyfus New Faculty Awards Program for support. We thank Dr. Eric Paulson and Dr. Christopher D. Incarvito for acquiring 205Tl NMR spectroscopic data and Prof. Adam R. Johnson for helpful comments.

Abstract

Abgeschirmt: Niedervalente Nickelzentren binden leicht und synthetisch reversibel Thallium(I)-Ionen, die wiederum die Koordinationsstellen des Nickelzentrums vor angreifenden Lewis-basischen Liganden schützen. Diese Synthesesequenz ermöglicht die Isolierung eines reaktiven, nullwertigen Nickel- Tris(isocyanid)-Komplexes.

original image
Get access to the full text of this article

Ancillary