Get access

Catalytic Oxidative Synthesis of Nitriles Directly from Primary Alcohols and Ammonia

Authors

  • Takamichi Oishi,

    1. Department of Applied Chemistry, School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656 (Japan), Fax: (+81) 3-5841-7220
    Search for more papers by this author
  • Kazuya Yamaguchi Dr.,

    1. Department of Applied Chemistry, School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656 (Japan), Fax: (+81) 3-5841-7220
    2. Core Research for Evolutional Science and Technology (CREST) (Japan) Science and Technology Agency, 4-1-8 Honcho, Kawaguchi, Saitama, 332-0012 (Japan)
    Search for more papers by this author
  • Noritaka Mizuno Prof. Dr.

    1. Department of Applied Chemistry, School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656 (Japan), Fax: (+81) 3-5841-7220
    2. Core Research for Evolutional Science and Technology (CREST) (Japan) Science and Technology Agency, 4-1-8 Honcho, Kawaguchi, Saitama, 332-0012 (Japan)
    Search for more papers by this author

  • This work was supported in part by the Global COE Program (Chemistry Innovation through Cooperation of Science and Engineering), the Core Research for Evolutional Science and Technology (CREST) program of the Japan Science and Technology Agency (JST), and Grants-in-Aid for Scientific Research from Ministry of Education, Culture, Sports, Science and Technology.

Abstract

original image

Gute Grundlage: Der Rutheniumhydroxid-Trägerkatalysator Ru(OH)x/Al2O3 vermittelt effizient die aerobe oxidative Synthese von Nitrilen direkt aus primären Alkoholen (oder Aldehyden) und Ammoniak. Der zurückgewonnene Katalysator konnte ohne merklichen Leistungsverlust wiederverwendet werden.

Ancillary