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Structural Tracking of a Bimolecular Reaction in Solution by Time-Resolved X-Ray Scattering

Authors

  • Kristoffer Haldrup Dr.,

    1. Centre for Molecular Movies, Department of Chemistry and Niels Bohr Institute, University of Copenhagen, Universitetsparken 5, 2100 Copenhagen (Denmark), Fax: (+45) 3532-0460
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  • Morten Christensen,

    1. Centre for Molecular Movies, Department of Chemistry and Niels Bohr Institute, University of Copenhagen, Universitetsparken 5, 2100 Copenhagen (Denmark), Fax: (+45) 3532-0460
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  • Marco Cammarata Dr.,

    1. European Synchrotron Radiation Facility, Grenoble Cedex 38043 (France)
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  • Qingyu Kong Dr.,

    1. European Synchrotron Radiation Facility, Grenoble Cedex 38043 (France)
    2. Current address: Société Civile Synchrotron SOLEIL, Gif-sur-Yvette Cedex 9112 (France)
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  • Michael Wulff Prof.,

    1. European Synchrotron Radiation Facility, Grenoble Cedex 38043 (France)
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  • Simon O. Mariager,

    1. Centre for Molecular Movies, Department of Chemistry and Niels Bohr Institute, University of Copenhagen, Universitetsparken 5, 2100 Copenhagen (Denmark), Fax: (+45) 3532-0460
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  • Klaus Bechgaard Prof.,

    1. Centre for Molecular Movies, Department of Chemistry and Niels Bohr Institute, University of Copenhagen, Universitetsparken 5, 2100 Copenhagen (Denmark), Fax: (+45) 3532-0460
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  • Robert Feidenhans'l Prof.,

    1. Centre for Molecular Movies, Department of Chemistry and Niels Bohr Institute, University of Copenhagen, Universitetsparken 5, 2100 Copenhagen (Denmark), Fax: (+45) 3532-0460
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  • Niels Harrit Prof.,

    1. Centre for Molecular Movies, Department of Chemistry and Niels Bohr Institute, University of Copenhagen, Universitetsparken 5, 2100 Copenhagen (Denmark), Fax: (+45) 3532-0460
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  • Martin M. Nielsen Prof.

    1. Centre for Molecular Movies, Department of Chemistry and Niels Bohr Institute, University of Copenhagen, Universitetsparken 5, 2100 Copenhagen (Denmark), Fax: (+45) 3532-0460
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  • The expert assistance provided by E. Pontecorvo and F. Ewald at the ID09B Beamline at ESRF, Grenoble, is very much appreciated. This work was supported by the Danish National Research Foundation’s Centre for Molecular Movies and DANSCATT.

Abstract

Molekülfilm: Zeitauflösende Röntgenbeugungsstudien lieferten direkte Informationen über die Struktur eines elektronisch angeregten Komplexes während seiner Bildung in der bimolekularen Reaktion zwischen angeregten Octawasserstoff[tetrakis-μ-diphosphito-1κP:2κP′-diplatinat](4-)-Ionen (PtPOP*) und Thalliumionen. Im Exciplex sind ein Thallium(I)- und zwei Platin(II)-Ionen kollinear.

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