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Metal-Ion-Coated Graphitic Nanotubes: Controlled Self-Assembly of a Pyridyl-Appended Gemini-Shaped Hexabenzocoronene Amphiphile

Authors

  • Wei Zhang,

    1. Department of Chemistry and Biotechnology, School of Engineering and Center for NanoBio Integration, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656 (Japan), Fax: (+81) 3-5841-7310
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  • Wusong Jin Dr.,

    1. ERATO-SORST Nanospace Project (Japan) Science and Technology Agency (JST), National Museum of Emerging Science and Innovation, 2-41 Aomi, Koto-ku, Tokyo 135-0064 (Japan)
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  • Takanori Fukushima Dr.,

    1. Department of Chemistry and Biotechnology, School of Engineering and Center for NanoBio Integration, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656 (Japan), Fax: (+81) 3-5841-7310
    2. Functional Soft Matter Engineering Laboratory, Advanced Science Institute, RIKEN, 2-1 Hirosawa, Wako, Saitama 351-0198 (Japan)
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  • Noriyuki Ishii Dr.,

    1. Institute for Biological Resources and Functions, National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba Central-6, 1-1-1 Higashi, Tsukuba, Ibaraki 305-8566 (Japan)
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  • Takuzo Aida Prof. Dr.

    1. ERATO-SORST Nanospace Project (Japan) Science and Technology Agency (JST), National Museum of Emerging Science and Innovation, 2-41 Aomi, Koto-ku, Tokyo 135-0064 (Japan)
    2. Department of Chemistry and Biotechnology, School of Engineering and Center for NanoBio Integration, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656 (Japan), Fax: (+81) 3-5841-7310
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Abstract

Nanoröhren vom Fließband: Hexabenzocoronen(HBC)-Amphiphile mit pyridylterminierten Triethylenglycol-Seitenketten bilden in Kombination mit trans-[Pt(PhCN)2Cl2] graphitische Nanoröhren. Die Strukturen und Abmessungen der Nanoröhren hängen dabei von den Synthesebedingungen ab. Auch Platin(II)-verbrückte cyclische Dimere mit zwei HBC-Einheiten bauen Nanoröhren auf.

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