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Palladium-Catalyzed Direct Arylation of Cyclic Enamides with Aryl Silanes by sp2 C[BOND]H Activation

Authors

  • Hai Zhou,

    1. Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, Singapore 637371 (Singapore), Fax: (+65) 6515-8229
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  • Yun-He Xu,

    1. Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, Singapore 637371 (Singapore), Fax: (+65) 6515-8229
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  • Wan-Jun Chung,

    1. Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, Singapore 637371 (Singapore), Fax: (+65) 6515-8229
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  • Teck-Peng Loh Prof.

    1. Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, Singapore 637371 (Singapore), Fax: (+65) 6515-8229
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  • We gratefully acknowledge the Nanyang Technological University and the Singapore Ministry of Education Academic Research Fund Tier 2 (T206B1221; T207B1220RS) for the financial support of this research.

Abstract

Aus H wird Ar: Eine fluoridunterstützte direkte Kreuzkupplung zwischen cyclischen Enamiden und Trialkoxyarylsilanen über eine palladiumkatalysierte C-H-Aktivierung liefert eine große Bandbreite an Enamiden in Ausbeuten bis 95 %.

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