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Bottom-Up Synthesis of Porous Coordination Frameworks: Apical Substitution of a Pentanuclear Tetrahedral Precursor

Authors

  • Xin-Long Wang Prof.,

    1. Institute of Functional Materials Chemistry, Key Laboratory of Polyoxometalate Science of Ministry of Education, Department of Chemistry, Northeast Normal University, Changchun, Jilin, 130024 (China)
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  • Chao Qin Prof.,

    1. Institute of Functional Materials Chemistry, Key Laboratory of Polyoxometalate Science of Ministry of Education, Department of Chemistry, Northeast Normal University, Changchun, Jilin, 130024 (China)
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  • Shui-Xing Wu Dr.,

    1. Institute of Functional Materials Chemistry, Key Laboratory of Polyoxometalate Science of Ministry of Education, Department of Chemistry, Northeast Normal University, Changchun, Jilin, 130024 (China)
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  • Kui-Zhan Shao Dr.,

    1. Institute of Functional Materials Chemistry, Key Laboratory of Polyoxometalate Science of Ministry of Education, Department of Chemistry, Northeast Normal University, Changchun, Jilin, 130024 (China)
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  • Ya-Qian Lan Dr.,

    1. Institute of Functional Materials Chemistry, Key Laboratory of Polyoxometalate Science of Ministry of Education, Department of Chemistry, Northeast Normal University, Changchun, Jilin, 130024 (China)
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  • Shuang Wang Dr.,

    1. Institute of Functional Materials Chemistry, Key Laboratory of Polyoxometalate Science of Ministry of Education, Department of Chemistry, Northeast Normal University, Changchun, Jilin, 130024 (China)
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  • Dong-Xia Zhu Prof.,

    1. Institute of Functional Materials Chemistry, Key Laboratory of Polyoxometalate Science of Ministry of Education, Department of Chemistry, Northeast Normal University, Changchun, Jilin, 130024 (China)
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  • Zhong-Min Su Prof.,

    1. Institute of Functional Materials Chemistry, Key Laboratory of Polyoxometalate Science of Ministry of Education, Department of Chemistry, Northeast Normal University, Changchun, Jilin, 130024 (China)
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  • En-Bo Wang Prof.

    1. Institute of Functional Materials Chemistry, Key Laboratory of Polyoxometalate Science of Ministry of Education, Department of Chemistry, Northeast Normal University, Changchun, Jilin, 130024 (China)
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  • This work was financially supported by the Program for Changjiang Scholars and Innovative Research Team in University, the National Natural Science Foundation of China (no. 20701006), the Foundation for Excellent Youth of Jilin, China (no. 20070103), and the Ph.D. Station Foundation of Ministry of Education for New Teachers (no. 20070200014/20070200015). We thank Prof. X. M. Chen of Sun Yat-Sen University for assistance with adsorption experiments and three referees for their helpful comments.

Abstract

Mikroporöse verzahnte Diamantgerüste lassen sich aus einem fünfkernigen tetraedrischen Komplex mit Nitratgruppen an den apicalen Positionen als anorganischer Vorstufe aufbauen. Ein „Bottom-up“-Verfahren wurde für den Ersatz der Nitratgruppen durch lineare ditope Carboxylatliganden genutzt (siehe Bild). Die Langmuir-Oberfläche der gebildeten Gerüste ist größer als die klassischer Zeolithe.

original image

Ancillary