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Micelles and Vesicles Formed by Polyoxometalate–Block Copolymer Composites


  • W.B. is grateful for a JSPS Fellowship. This work was supported by the Core Research for Evolutional Science and Technology (CREST) program of Japan Science and Technology Agency (JST), and Grants-in-Aid for Scientific Research, Center for Nano Lithography and Analysis, and The University of Tokyo Global COE Program Chemistry through Cooperation of Science and Engineering from the Ministry of Education, Culture, Sports, Science, and Technology (MEXT) of Japan. Drs. H. S. Kato (RIKEN) and S. Inasawa (Univ. of Tokyo) are acknowledged for the SFM measurements. Rigaku corporation is acknowledged for the SAXS and XRF measurements.


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Kern-Schale-Komposite wurden durch Einbetten eines hydrophilen Polyoxometallats (POM) in Poly(styrol-b-4-vinyl-N-methylpyridiniumiodid)-Matrices in saurer wässriger Lösung erhalten (siehe Schema). Beim Dispergieren in Toluol entstehen selbstorganisierte Micell- und Vesikelstrukturen (siehe TEM-Bilder), deren Morphologie über den POM-Anteil gesteuert werden kann.

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