Zuschrift

The Determination of Methylmercury in Real Samples Using Organically Capped Mesoporous Inorganic Materials Capable of Signal Amplification†

  1. Estela Climent1,2,
  2. M. Dolores Marcos Dr.1,2,
  3. Ramón Martínez-Máñez Prof.1,2,
  4. Félix Sancenón Dr.1,2,
  5. Juan Soto Dr.1,2,
  6. Knut Rurack Dr.3,
  7. Pedro Amorós Prof.4

Article first published online: 2 OCT 2009

DOI: 10.1002/ange.200904243

Issue

Angewandte Chemie

Angewandte Chemie

Volume 121, Issue 45, pages 8671–8674, October 26, 2009

Additional Information

How to Cite

Climent, E., Marcos, M., Martínez-Máñez, R., Sancenón, F., Soto, J., Rurack, K. and Amorós, P. (2009), The Determination of Methylmercury in Real Samples Using Organically Capped Mesoporous Inorganic Materials Capable of Signal Amplification. Angewandte Chemie, 121: 8671–8674. doi: 10.1002/ange.200904243

Author Information

  1. 1

    Instituto de Reconocimiento Molecular y Desarrollo Tecnológico, Centro Mixto Universidad Politécnica de Valencia—Universidad de Valencia, Departamento de Química, Universidad Politécnica de Valencia, Camino de Vera s/n, 46022 Valencia (Spain), Fax: (+34) 96-387-9349

  2. 2

    CIBER de Bioingeniería, Biomateriales y Nanomedicina (CIBER-BBN)

  3. 3

    Div. I.5, BAM Bundesanstalt für Materialforschung und -prüfung Richard-Willstätter-Strasse 11, 12489 Berlin (Germany), Fax: (+49) 30-8104-1157

  4. 4

    Institut de Ciència del Materials (ICMUV), Universitat de València, P.O. Box 2085, 46071 València (Spain)

  1. †

    Financial support by the Spanish Ministerio de Ciencia y Tecnología (projects CTQ2006-15456-C04-01, MAT2009-14564-C04-01 and CIBER-BBN CB07/01/2012) is gratefully acknowledged. E.C. is grateful to the MICINN for a grant.

Publication History

  1. Issue published online: 20 OCT 2009
  2. Article first published online: 2 OCT 2009
  3. Manuscript Received: 30 JUL 2009

Funded by

  • Spanish Ministerio de Ciencia y Tecnología. Grant Numbers: CTQ2006-15456-C04-01, MAT2009-14564-C04-01, CIBER-BBN CB07/01/2012
  • MICINN

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Keywords:

  • Chemosensoren;
  • Fluoreszenz;
  • Mesoporöse Materialien;
  • Methylquecksilber

Graphical Abstract

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Die Affinität von Methylquecksilber zu Leukosquarain-Gruppen (weiß im Bild) bewirkt das Öffnen damit bedeckter Poren eines mesoporösen Hybridmaterials und das Freisetzen eingeschlossener Safraninfarbstoffe (orange), was den selektiven optischen Nachweis von Methylquecksilber in komplexen biologischen Proben ermöglicht.

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