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Coupling Reactions of Zirconate Complexes Induced by Carbonyl Compounds

Authors

  • Chanjuan Xi Prof.,

    1. Key Laboratory of Bioorganic Phosphorus Chemistry & Chemical Biology (Ministry of Education), Department of Chemistry, Tsinghua University, Beijing 100084 (China)
    2. State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin 300071 (China), Fax: (+86) 10-6277-1194
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  • Xiaoyu Yan,

    1. Key Laboratory of Bioorganic Phosphorus Chemistry & Chemical Biology (Ministry of Education), Department of Chemistry, Tsinghua University, Beijing 100084 (China)
    2. State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin 300071 (China), Fax: (+86) 10-6277-1194
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  • Wei You,

    1. Key Laboratory of Bioorganic Phosphorus Chemistry & Chemical Biology (Ministry of Education), Department of Chemistry, Tsinghua University, Beijing 100084 (China)
    2. State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin 300071 (China), Fax: (+86) 10-6277-1194
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  • Tamotsu Takahashi Prof.

    1. Catalysis Research Center and Graduate School of Life Science, Hokkaido University, Sapporo 001-0021 (Japan)
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  • We thank the National Natural Science Foundation of China (20872076), and the Doctoral Program of Higher Education (200800030072) for financial support. We also thank Dr. Haifang Li for her kind help with measurement of HRMS data.

Abstract

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Facettenreiches Organozirconat: Die neuartige Kupplungsreaktion von Organozirconaten 1 mit Carbonylverbindungen (über die Zwischenstufe 2) bietet einen selektiven Zugang zu hoch substituierten Allenen 3 und Dienolen 4.

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