Olefin Cyclopropanation by a Sequential Atom-Transfer Radical Addition and Dechlorination in the Presence of a Ruthenium Catalyst

Authors

  • Katrin Thommes,

    1. Institut des Sciences et Ingénierie Chimiques, École Polytechnique Fédérale de Lausanne (EPFL), 1015 Lausanne (Switzerland), Fax: (+41) 21-693-9305
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  • Gregor Kiefer,

    1. Institut des Sciences et Ingénierie Chimiques, École Polytechnique Fédérale de Lausanne (EPFL), 1015 Lausanne (Switzerland), Fax: (+41) 21-693-9305
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  • Rosario Scopelliti Dr.,

    1. Institut des Sciences et Ingénierie Chimiques, École Polytechnique Fédérale de Lausanne (EPFL), 1015 Lausanne (Switzerland), Fax: (+41) 21-693-9305
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  • Kay Severin Prof.

    1. Institut des Sciences et Ingénierie Chimiques, École Polytechnique Fédérale de Lausanne (EPFL), 1015 Lausanne (Switzerland), Fax: (+41) 21-693-9305
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  • This work was supported by the Swiss National Science Foundation and by the EPFL.

Abstract

original image

Ganz ohne Diazo: Die reduktive Kupplung von Olefinen mit Dichlorverbindungen in Gegenwart von Magnesium und einem Rutheniumkatalysator liefert in guter Ausbeute Cyclopropane (siehe Schema).

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