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Oxidative Addition of Halogens on Open Metal Sites in a Microporous Spin-Crossover Coordination Polymer

Authors

  • Gloria Agustí Dr.,

    1. Instituto de Ciencia Molecular (ICMol)/, Departamento de Química Inorgánica, Universidad de Valencia, Edificio de Institutos de Paterna, Apartado de correos 22085, 46071 Valencia (Spain)
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  • Ryo Ohtani,

    1. Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University Katsura, Nishikyo-ku, Kyoto 615-8510 (Japan)
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  • Ko Yoneda,

    1. Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University Katsura, Nishikyo-ku, Kyoto 615-8510 (Japan)
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  • Ana B. Gaspar Dr.,

    1. Instituto de Ciencia Molecular (ICMol)/, Departamento de Química Inorgánica, Universidad de Valencia, Edificio de Institutos de Paterna, Apartado de correos 22085, 46071 Valencia (Spain)
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  • Masaaki Ohba Dr.,

    1. Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University Katsura, Nishikyo-ku, Kyoto 615-8510 (Japan)
    2. RIKEN Spring-8 Center, Kouto, Sayo-cho, Sayo-gun, Hyogo 679-5198 (Japan)
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  • Juan F. Sánchez-Royo Dr.,

    1. Instituto de Ciencia de los Materiales de la Universidad de Valencia, Universidad de Valencia, Doctor Moliner 50, 46100 Burjassot Valencia (Spain)
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  • M. Carmen Muñoz Prof. Dr.,

    1. Departamento de Física Aplicada, Universitad Politécnica de Valencia, Camino de Vera s/n, 46022 Valencia (Spain)
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  • Susumu Kitagawa Prof. Dr.,

    1. Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University Katsura, Nishikyo-ku, Kyoto 615-8510 (Japan)
    2. RIKEN Spring-8 Center, Kouto, Sayo-cho, Sayo-gun, Hyogo 679-5198 (Japan)
    3. Institute for Integrated Cell-Material Sciences (iCeMS), Yoshida, Sakyo-ku, Kyoto 606-8501 (Japan)
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  • José A. Real Prof. Dr.

    1. Instituto de Ciencia Molecular (ICMol)/, Departamento de Química Inorgánica, Universidad de Valencia, Edificio de Institutos de Paterna, Apartado de correos 22085, 46071 Valencia (Spain)
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  • This work was supported by a ERATO JST Project “Kitagawa Integrated Pore Project”, CREST JST, the Spanish Ministerio de Ciencia e Innovación (MICINN) and FEDER funds, (CTQ2007-64727) and the Generalitat Valenciana funds (ACOMP/2009/326). A.B.G. thanks the MICINN for a Ramon y Cajal research contract. G.A. thanks the network MAGMANet, a network of excellence of the European Union (Contract: NMP3-CT-2005-515767-2) for a predoctoral grant.

Abstract

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Innige Verbindung: Die Einwirkung von X2 (Cl2, Br2, I2) auf das poröse Spin-Crossover-Material {Fe(pz)[PtII(CN)4]} (pz=Pyrazin) führt durch oxidative Addition zum Halogenid-Einbau in die koordinativ ungesättigten [PtII(CN)4]2−-Einheiten. Eine Serie gemischtvalenter {Fe(pz)[PtII/IV(CN)4(X)]}-Gerüste mit charakteristischem kooperativem Spinübergang wurde erhalten.

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