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Concise One-Pot Tandem Synthesis of Indoles and Isoquinolines from Amides

Authors

  • Noriko Okamoto,

    1. Faculty of Pharmaceutical Sciences, Hiroshima International University, 5-1-1 Hirokoshingai, Kure , Hiroshima 737-0112 (Japan), Fax: (+81) 823-73-8981
    2. Department of Synthetic Organic Chemistry, Graduate School of Medical Sciences, Hiroshima University, 1-2-3 Kasumi, Minami-Ku, Hiroshima 734-8553 (Japan)
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  • Yoshihisa Miwa Prof. Dr.,

    1. Faculty of Pharmaceutical Sciences, Hiroshima International University, 5-1-1 Hirokoshingai, Kure , Hiroshima 737-0112 (Japan), Fax: (+81) 823-73-8981
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  • Hideki Minami,

    1. Faculty of Pharmaceutical Sciences, Hiroshima International University, 5-1-1 Hirokoshingai, Kure , Hiroshima 737-0112 (Japan), Fax: (+81) 823-73-8981
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  • Kei Takeda Prof. Dr.,

    1. Department of Synthetic Organic Chemistry, Graduate School of Medical Sciences, Hiroshima University, 1-2-3 Kasumi, Minami-Ku, Hiroshima 734-8553 (Japan)
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  • Reiko Yanada Prof. Dr.

    1. Faculty of Pharmaceutical Sciences, Hiroshima International University, 5-1-1 Hirokoshingai, Kure , Hiroshima 737-0112 (Japan), Fax: (+81) 823-73-8981
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  • This work was supported by a Grant-in-Aid for Scientific Research(C) from JSPS KAKENHI (20590027).

Abstract

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Einfach zu Heterocyclen: Platin(II)-katalysierte Synthesen von Indolen und Isochinonen aus Isocyanaten – hergestellt mithilfe eines hypervalenten Iodreagens durch eine Amidumlagerung vom Hofmann-Typ – werden vorgestellt. Auch C2-symmetrische makrocyclische Bis(indole) sind zugänglich, und zwar durch Transanellierung C2-symmetrischer makrocyclischer Bis(alkincarbamat)-Zwischenstufen.

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