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Asymmetric Organocatalytic Relay Cascades: Catalyst-Controlled Stereoisomer Selection in the Synthesis of Functionalized Cyclohexanes

Authors

  • Yao Wang,

    1. State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000 (China), Fax: (+86) 931-891-5557
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  • Rong-Gang Han,

    1. State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000 (China), Fax: (+86) 931-891-5557
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  • Yong-Long Zhao,

    1. State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000 (China), Fax: (+86) 931-891-5557
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  • Shu Yang,

    1. State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000 (China), Fax: (+86) 931-891-5557
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  • Peng-Fei Xu Prof. Dr.,

    1. State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000 (China), Fax: (+86) 931-891-5557
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  • Darren J. Dixon Prof. Dr.

    1. Department of Chemistry, Chemistry Research Laboratory, University of Oxford, Mansfield Road, Oxford, OX1 3TA (UK), Fax: (+44) 1865-285-002
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  • We are grateful for the financial support of “973” project (2009CB626604) from MOST, the foundation (20772051) from NSFC, the “111” program from MOE of P. R. China, the EPSRC for a Leadership fellowship to D.J.D.

Abstract

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Stabübergabe: Eine Staffelkaskade liefert Cyclohexane direkt, effizient und stereoselektiv. Die Dreifachkaskade hat ein breites Substratspektrum, und unterschiedliche Diastereomere sind einfach durch geschickte Wahl der Organokatalysatoren zugänglich.

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