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Gold–Silane and Gold–Stannane Complexes: Saturated Molecules as σ-Acceptor Ligands

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  • Financial support from the Centre National de la Recherche Scientifique, the Université de Toulouse, the Agence Nationale de la Recherche (ANR-06-BLAN-0034), the National Science Foundation (CHE-0646916), and the Welch Foundation (A-1423) is gratefully acknowledged. We thank: the Unidade de RaiosX of the Universidade de Santiago de Compostela for the X-ray diffraction analyses of 4 and 5; Christopher Cummins (MIT) for useful discussions regarding the use of the Dgrid program; the Laboratory for Molecular Simulation at Texas A&M University for providing software and computation resources. L.M. thanks the Institut Universitaire de France and D.B. thanks the COST action CM0802 PhoSciNet for supporting this work.

Abstract

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Gold findet Halt: Spektroskopische, strukturchemische und computergestützte Studien liefern Belege für neuartige Au→Si- und Au→Sn-Wechselwirkungen in Gold(I)-Komplexen, die mit diphosphanylsubstituierten Silan- bzw. Stannanliganden erhalten wurden (siehe Schema).

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