We are grateful for support provided by the Chemical Sciences, Geosciences, and Biosciences Division, Office of Basic Energy Sciences, Office of Science, Heavy Elements Program, U.S. Department of Energy, under Grants DE-FG02-01ER15187, DE-FG02-01ER16026. This material is based upon work supported as part of the Materials Science of Actinides, an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences under Award Number DE-SC0001089, by Deutsche Forschungsgemeinschaft for support within the DE 412/30-2 research project, and under contract DE-AC02-06CH11357 at Argonne National Laboratory. We thank Professors Gregory S. Girolami and Peter C. Burns for helpful discussions.
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Neptunium Diverges Sharply from Uranium and Plutonium in Crystalline Borate Matrixes: Insights into the Complex Behavior of the Early Actinides Relevant to Nuclear Waste Storage†
Article first published online: 18 JAN 2010
DOI: 10.1002/ange.200906127
Copyright © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
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How to Cite
Wang, S., Alekseev, Evgeny V., Ling, J., Skanthakumar, S., Soderholm, L., Depmeier, W. and Albrecht-Schmitt, Thomas E. (2010), Neptunium Diverges Sharply from Uranium and Plutonium in Crystalline Borate Matrixes: Insights into the Complex Behavior of the Early Actinides Relevant to Nuclear Waste Storage. Angew. Chem., 122: 1285–1288. doi: 10.1002/ange.200906127
- †
Publication History
- Issue published online: 1 FEB 2010
- Article first published online: 18 JAN 2010
- Manuscript Received: 30 OCT 2009
Funded by
- Chemical Sciences, Geosciences, and Biosciences Division, Office of Basic Energy Sciences, Office of Science, Heavy Elements Program, U.S. Department of Energy. Grant Numbers: FG02-01ER15187, DE-FG02-01ER16026, DE-SC0001089
- Deutsche Forschungsgemeinschaft. Grant Number: DE 412/30-2
- Argonne National Laboratory
Keywords:
- Actinoide;
- Borate;
- Festphasenreaktionen;
- Gemischtvalente Verbindungen;
- Redoxchemie
Anders als die anderen: Neptuniumborate unterscheiden sich von Uran- und Plutoniumboraten: Sie liegen als gemischtvalente Verbindungen mit jeweils dreierlei Koordinationsumgebungen und Oxidationstufen vor (siehe Bild; Polyeder: NpIV hellblau, NpV dunkelblau, NpVI grün, B gelb; Kugeln: O rot, K oder Ba blau).