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Ionothermal Synthesis of Extra-Large-Pore Open-Framework Nickel Phosphite 5 H3O⋅[Ni8(HPO3)9Cl3]⋅1.5 H2O: Magnetic Anisotropy of the Antiferromagnetism

Authors

  • Hongzhu Xing,

    1. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012 (P. R. China), Fax: (+86) 431-8516-8608
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  • Weiting Yang,

    1. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012 (P. R. China), Fax: (+86) 431-8516-8608
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  • Tan Su,

    1. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012 (P. R. China), Fax: (+86) 431-8516-8608
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  • Yi Li Dr.,

    1. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012 (P. R. China), Fax: (+86) 431-8516-8608
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  • Jin Xu,

    1. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012 (P. R. China), Fax: (+86) 431-8516-8608
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  • Takehito Nakano Prof.,

    1. Department of Physics, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043 (Japan)
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  • Jihong Yu Prof.,

    1. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012 (P. R. China), Fax: (+86) 431-8516-8608
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  • Ruren Xu Prof.

    1. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012 (P. R. China), Fax: (+86) 431-8516-8608
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  • We thank the National Natural Science Foundation of China, the State Basic Research Project of China (grants 2006CB806103 and 2007CB936402), and the Major International Collaboration Project of China for financial support for this work. T.N. acknowledges a Grant-in-Aid for Scientific Research on Priority Areas (No. 19051009) and a Grant-in-Aid for Young Scientists B (no. 20710077) from MEXT (Japan).

Abstract

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Mikroporöse Magnete: Die Struktur der Titelverbindung (siehe Einschub) weist zweidimensionale Nickel-Sauerstoff/Chlorid-18-Ring-Schichten auf, die entlang der c-Achse gestapelt und durch HPO3-Einheiten verknüpft sind. Nach Messungen der magnetischen Anisotropie an ausgerichteten Einkristallen (siehe Graph) ist die leichte magnetische Achse senkrecht zur Schichtebene.

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