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Titelbild: Heterogeneously Hybridized Porous Coordination Polymer Crystals: Fabrication of Heterometallic Core–Shell Single Crystals with an In-Plane Rotational Epitaxial Relationship (Angew. Chem. 10/2009)

Authors

  • Shuhei Furukawa Dr.,

    1. ERATO Kitagawa Integrated Pores Project (Japan), Kyoto Research Park Bldg #3, Shimogyo-ku, Kyoto 600-8815 (Japan), Fax: (+81) 75-325-3572 http://kip.jst.go.jp
    2. Institute for Integrated Cell-Material Sciences (iCeMS), Kyoto University, Yoshida, Sakyo-ku, Kyoto 606-8501 (Japan)
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  • Kenji Hirai,

    1. Department of Synthetic Chemistry & Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510 (Japan)
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  • Keiji Nakagawa,

    1. Department of Synthetic Chemistry & Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510 (Japan)
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  • Yohei Takashima,

    1. Department of Synthetic Chemistry & Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510 (Japan)
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  • Ryotaro Matsuda Dr.,

    1. ERATO Kitagawa Integrated Pores Project (Japan), Kyoto Research Park Bldg #3, Shimogyo-ku, Kyoto 600-8815 (Japan), Fax: (+81) 75-325-3572 http://kip.jst.go.jp
    2. Institute for Integrated Cell-Material Sciences (iCeMS), Kyoto University, Yoshida, Sakyo-ku, Kyoto 606-8501 (Japan)
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  • Takaaki Tsuruoka Dr.,

    1. ERATO Kitagawa Integrated Pores Project (Japan), Kyoto Research Park Bldg #3, Shimogyo-ku, Kyoto 600-8815 (Japan), Fax: (+81) 75-325-3572 http://kip.jst.go.jp
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  • Mio Kondo Dr.,

    1. Institute for Integrated Cell-Material Sciences (iCeMS), Kyoto University, Yoshida, Sakyo-ku, Kyoto 606-8501 (Japan)
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  • Rie Haruki Dr.,

    1. Research & Utilization Division (Japan), Synchrotron Radiation Research Institute/SPring-8 and CREST, JST, Kouto, Sayo, Hyogo 679-5198 (Japan)
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  • Daisuke Tanaka Dr.,

    1. Department of Synthetic Chemistry & Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510 (Japan)
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  • Hirotoshi Sakamoto,

    1. Department of Synthetic Chemistry & Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510 (Japan)
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  • Satoru Shimomura,

    1. Department of Synthetic Chemistry & Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510 (Japan)
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  • Osami Sakata Dr.,

    1. Research & Utilization Division (Japan), Synchrotron Radiation Research Institute/SPring-8 and CREST, JST, Kouto, Sayo, Hyogo 679-5198 (Japan)
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  • Susumu Kitagawa Prof.

    1. ERATO Kitagawa Integrated Pores Project (Japan), Kyoto Research Park Bldg #3, Shimogyo-ku, Kyoto 600-8815 (Japan), Fax: (+81) 75-325-3572 http://kip.jst.go.jp
    2. Institute for Integrated Cell-Material Sciences (iCeMS), Kyoto University, Yoshida, Sakyo-ku, Kyoto 606-8501 (Japan)
    3. Department of Synthetic Chemistry & Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510 (Japan)
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Abstract

Ein poröses Kupferkoordinationsgerüst wuchs epitaktisch als Einkristall auf der Einkristalloberfläche eines porösen Zinkkoordinationsgerüsts, wie S. Kitagawa et al. in ihrer Zuschrift auf S. 1798 ff. beschreiben. Im Bild sind die Strukturbeziehungen zwischen dem Kupfer- und dem Zinkgerüst zu sehen, die durch röntgenographische Untersuchung der Oberflächen mit Synchrotronstrahlung erhalten wurden; epitaktisches Wachstum in der Ebene unter Rotation kompensiert die unterschiedlichen Gitterkonstanten der beiden Kristalle.

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