Boron- and Fluorine-Containing Mesoporous Carbon Nitride Polymers: Metal-Free Catalysts for Cyclohexane Oxidation

Authors

  • Yong Wang Dr.,

    1. Department of Colloid Chemistry, Max-Planck Institute of Colloids and Interfaces, Research Campus Golm, 14424 Potsdam (Germany), Fax: (+49) 331-567-9502
    2. Department of Chemistry, Zhejiang University, Hangzhou 310027 (China)
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  • Jinshui Zhang,

    1. Research Institute of Photocatalysis, State Key Laboratory Breeding Base of Photocatalysis, Fuzhou University, Fuzhou 350002 (China)
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  • Xinchen Wang Prof. Dr.,

    1. Department of Colloid Chemistry, Max-Planck Institute of Colloids and Interfaces, Research Campus Golm, 14424 Potsdam (Germany), Fax: (+49) 331-567-9502
    2. Research Institute of Photocatalysis, State Key Laboratory Breeding Base of Photocatalysis, Fuzhou University, Fuzhou 350002 (China)
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  • Markus Antonietti Prof. Dr.,

    1. Department of Colloid Chemistry, Max-Planck Institute of Colloids and Interfaces, Research Campus Golm, 14424 Potsdam (Germany), Fax: (+49) 331-567-9502
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  • Haoran Li Prof. Dr.

    1. Department of Chemistry, Zhejiang University, Hangzhou 310027 (China)
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  • This work was supported by the ENERCHEM project of the MPI, by the National Natural Science Foundation of China (No. 20806065), and by the China Postdoctoral Special Science Foundation funded project (No. 200902630).

Abstract

original image

Aufgepeppt mit B und F: Das Titelsystem wurde in einem simplen Einstufenprozess mit 1-Butyl-3-methylimidazoliumtetrafluoroborat als weichem Templat synthetisiert. Die erhaltenen Materialien haben eine „Morchel-artige“ mesoporöse Struktur (siehe Bild) mit schmaler Porengrößenverteilung und guter Photoaktivität unter sichtbarem Licht. Es sind gute Katalysatoren für die selektive Cyclohexanoxidation.

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