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Sensitive and Selective Chromogenic Sensing of Carbon Monoxide by Using Binuclear Rhodium Complexes†

  1. Julio Esteban Dr.,
  2. José Vicente Ros-Lis Dr.,
  3. Ramón Martínez-Máñez Prof.,
  4. M. Dolores Marcos Dr.,
  5. María Moragues,
  6. Juan Soto Dr.,
  7. Félix Sancenón Dr.

Article first published online: 2 JUN 2010

DOI: 10.1002/ange.201001344

Issue

Angewandte Chemie

Angewandte Chemie

Volume 122, Issue 29, pages 5054–5057, July 5, 2010

Additional Information

How to Cite

Esteban, J., Ros-Lis, J., Martínez-Máñez, R., Marcos, M. Dolores., Moragues, M., Soto, J. and Sancenón, F. (2010), Sensitive and Selective Chromogenic Sensing of Carbon Monoxide by Using Binuclear Rhodium Complexes. Angew. Chem., 122: 5054–5057. doi: 10.1002/ange.201001344

Author Information

  1. Instituto de Reconocimiento Molecular y Desarrollo Tecnológico, Centro Mixto Universidad Politécnica de Valencia—, Universidad de Valencia, Departamento de Química, Universidad Politécnica de Valencia, Camino de Vera s/n, 46022 Valencia (Spain) and CIBER de Bioingeniería, Biomateriales y Nanomedicina (CIBER-BBN), Fax: (+34) 96-387-9349http://idm.webs.upv.es/

  1. †

    Financial support by the Spanish Government (project MAT2009-14564-C04-01) and the Generalitat Valencia (project PROMETEO/2009/016) is gratefully acknowledged. We thank M. Liu-Gonzalez of the SCSIE of the Universitat de Valencia (Spain) for single-crystal data collection and kind support in structure solution.

Publication History

  1. Issue published online: 29 JUN 2010
  2. Article first published online: 2 JUN 2010
  3. Manuscript Received: 5 MAR 2010

Funded by

  • Spanish Government. Grant Number: MAT2009-14564-C04-01
  • Generalitat Valencia. Grant Number: PROMETEO/2009/016

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Keywords:

  • Chromogener Nachweis;
  • Kohlenmonoxid;
  • Rhodium;
  • Sensoren;
  • Zweikernige Komplexe
Thumbnail image of graphical abstract

CO-Fänger: Kohlenmonoxid kann mit dem zweikernigen Rhodiumkomplex cis-[Rh2(C6H4PPh2)2(O2CCH3)2](HO2CCH3)2 selektiv und empfindlich nachgewiesen werden. Der Komplex, der zwei cyclometallierte Phosphanliganden enthält, koordiniert CO axial und ändert dabei seine Farbe von Violett nach Orangegelb (siehe Bild).

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