Monomeric Organoantimony(I) and Organobismuth(I) Compounds Stabilized by an NCN Chelating Ligand: Syntheses and Structures

Authors

  • Petr Šimon Ing.,

    1. Department of General and Inorganic Chemistry, Faculty of Chemical Technology, University of Pardubice, Studentská 573, Pardubice 53210 (Czech Republic), Fax: (+42) 40-6603-7068
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  • Frank de Proft Prof.,

    1. Eenheid Algemene Chemie (ALGC), Vrije Universiteit Brussel (VUB), Pleinlaan 2, 1050 Brussels (Belgium)
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  • Roman Jambor Prof.,

    1. Department of General and Inorganic Chemistry, Faculty of Chemical Technology, University of Pardubice, Studentská 573, Pardubice 53210 (Czech Republic), Fax: (+42) 40-6603-7068
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  • Aleš Růžička Prof.,

    1. Department of General and Inorganic Chemistry, Faculty of Chemical Technology, University of Pardubice, Studentská 573, Pardubice 53210 (Czech Republic), Fax: (+42) 40-6603-7068
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  • Libor Dostál Dr.

    1. Department of General and Inorganic Chemistry, Faculty of Chemical Technology, University of Pardubice, Studentská 573, Pardubice 53210 (Czech Republic), Fax: (+42) 40-6603-7068
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  • The authors thank the GAČR (P207/10/0130) and the Ministry of Education of the Czech Republic (MSM0021627501) for financial support. F.D.P. wishes to acknowledge the Fund for Scientific Research Flanders (Belgium) FWO and the Vrije Universiteit Brussel for financial support.

Abstract

original image

Soloauftritt: Dank einer Kombination von sterischen Effekten und M-N-Wechselwirkungen eines starren NCN-Pinzettenliganden gelang die Isolierung und Charakterisierung von monomeren Stibiniden- und Bismutinidenverbindungen. Die Strukturen und Bindungsverhältnisse wurden durch kristallographische Studien (siehe Bild; Sb oder Bi gelb, N blau) und Rechnungen bestätigt.

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