Metathesis Reaction of Hydrocarbyl Ligands across the Triruthenium Plane

Authors

  • Atsushi Tahara,

    1. Department of Applied Chemistry , Graduate School of Science and Engineering, Tokyo Institute of Technology, O-okayama, Meguro-ku, Tokyo 152-8552 (Japan), Fax: (+81) 3-5734-3913
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  • Mana Kajigaya,

    1. Department of Applied Chemistry , Graduate School of Science and Engineering, Tokyo Institute of Technology, O-okayama, Meguro-ku, Tokyo 152-8552 (Japan), Fax: (+81) 3-5734-3913
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  • Makoto Moriya Dr.,

    1. Department of Applied Chemistry , Graduate School of Science and Engineering, Tokyo Institute of Technology, O-okayama, Meguro-ku, Tokyo 152-8552 (Japan), Fax: (+81) 3-5734-3913
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  • Toshiro Takao Dr.,

    1. Department of Applied Chemistry , Graduate School of Science and Engineering, Tokyo Institute of Technology, O-okayama, Meguro-ku, Tokyo 152-8552 (Japan), Fax: (+81) 3-5734-3913
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  • Hiroharu Suzuki Prof.

    1. Department of Applied Chemistry , Graduate School of Science and Engineering, Tokyo Institute of Technology, O-okayama, Meguro-ku, Tokyo 152-8552 (Japan), Fax: (+81) 3-5734-3913
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  • This study was partially supported by Grant No. 18105002 (Scientific Research (S)) and Grant No. 18064007 (Priority Area “Synergy of Elements”) from the Ministry of Education, Culture, Sports, Science and Technology (Japan).

Abstract

original image

C3wechselt die Seite: Die Thermolyse eines Trirutheniumkomplexes mit einem μ3-Pentylidin- und einem μ3-Pentin-Liganden zu beiden Seiten der von den Metallatomen gebildeten Ebene führt ausschließlich zu einem μ3-Ethylidin-μ3-octin-Komplex. Bei dieser Reaktion wandert ein C3-Fragment von einer Seite der Ru3-Ebene auf die andere, was in einer Umverteilung von zwei C5- in ein C2- und ein C8-Molekül resultiert.

Ancillary