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Innentitelbild: Controlled Reducibility of a Metal–Organic Framework with Coordinatively Unsaturated Sites for Preferential Gas Sorption (Angew. Chem. 34/2010)

Authors

  • Ji Woong Yoon Dr.,

    1. Catalysis Center for Molecular Engineering, Korea Research Institute of Chemical Technology (KRICT), Jang-dong 100, Yuseong, Daejeon 305-600 (Korea), Fax: (+82) 42-860-7673
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  • You-Kyong Seo,

    1. Catalysis Center for Molecular Engineering, Korea Research Institute of Chemical Technology (KRICT), Jang-dong 100, Yuseong, Daejeon 305-600 (Korea), Fax: (+82) 42-860-7673
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  • Young Kyu Hwang Dr.,

    1. Catalysis Center for Molecular Engineering, Korea Research Institute of Chemical Technology (KRICT), Jang-dong 100, Yuseong, Daejeon 305-600 (Korea), Fax: (+82) 42-860-7673
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  • Jong-San Chang Dr.,

    1. Catalysis Center for Molecular Engineering, Korea Research Institute of Chemical Technology (KRICT), Jang-dong 100, Yuseong, Daejeon 305-600 (Korea), Fax: (+82) 42-860-7673
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  • Hervé Leclerc,

    1. Laboratoire Catalyse et Spectrochimie, UMR 6506, CNRS/ENSICAEN et Université de Caen Basse-Normandie (France)
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  • Stefan Wuttke Dr.,

    1. Laboratoire Catalyse et Spectrochimie, UMR 6506, CNRS/ENSICAEN et Université de Caen Basse-Normandie (France)
    2. Institut Lavoisier (UMR CNRS 8180), Université de Versailles Saint-Quentin-en-Yvelines, 45 avenue des Etats-Unis, 78035 Versailles cedex (France)
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  • Philippe Bazin,

    1. Laboratoire Catalyse et Spectrochimie, UMR 6506, CNRS/ENSICAEN et Université de Caen Basse-Normandie (France)
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  • Alexandre Vimont Dr.,

    1. Laboratoire Catalyse et Spectrochimie, UMR 6506, CNRS/ENSICAEN et Université de Caen Basse-Normandie (France)
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  • Marco Daturi Prof.,

    1. Laboratoire Catalyse et Spectrochimie, UMR 6506, CNRS/ENSICAEN et Université de Caen Basse-Normandie (France)
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  • Emily Bloch Dr.,

    1. Laboratoire Chimie Provence, UMR 6264, Universités Aix-Marseille I, II & III-CNRS (France)
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  • Philip L. Llewellyn Dr.,

    1. Laboratoire Chimie Provence, UMR 6264, Universités Aix-Marseille I, II & III-CNRS (France)
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  • Christian Serre Dr.,

    1. Institut Lavoisier (UMR CNRS 8180), Université de Versailles Saint-Quentin-en-Yvelines, 45 avenue des Etats-Unis, 78035 Versailles cedex (France)
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  • Patricia Horcajada Dr.,

    1. Institut Lavoisier (UMR CNRS 8180), Université de Versailles Saint-Quentin-en-Yvelines, 45 avenue des Etats-Unis, 78035 Versailles cedex (France)
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  • Jean-Marc Grenèche Dr.,

    1. Laboratoire de Physique de l'Etat Condensé, UMR CNRS 6087, Université du Maine (France)
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  • Alirio E. Rodrigues Prof.,

    1. Laboratory of Separation and Reaction Engineering, Department of Chemical Engineering, University of Porto (Portugal)
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  • Gérard Férey Prof.

    1. Institut Lavoisier (UMR CNRS 8180), Université de Versailles Saint-Quentin-en-Yvelines, 45 avenue des Etats-Unis, 78035 Versailles cedex (France)
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Abstract

original image

Die steuerbare Reduzierbarkeit koordinativ ungesättigter Eisenzentren in MIL-100(Fe), [Fe3O(H2O)2F0.81(OH)0.19{C6H3(CO2)3}2]⋅14.5 H2O, wird von J.-S. Chang et al. in der Zuschrift auf S. 6085 ff. beschrieben. Durch thermische Aktivierung von MIL-100(Fe) entstehen koordinativ ungesättigte Zentren mit gemischtvalentem FeII/FeIII, was zu einer Sorptionsselektivität für ungesättigte Gasmoleküle wie Propylen führt.

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