The EPSRC and the ERC (FUNCAT- Advanced Investigator Award to S.P.N.) are gratefully acknowledged for support of this work. Chemetall are thanked for their generous gift of materials. S.P.N. is a Royal Society Wolfson Research Merit Award holder.
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Zuschrift
Carboxylation of N![[BOND]](http://onlinelibrarystatic.wiley.com/undisplayable_characters/00f8ff.gif)
H/CH Bonds Using N-Heterocyclic Carbene Copper(I) Complexes†
Article first published online: 30 SEP 2010
DOI: 10.1002/ange.201004153
Copyright © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
Additional Information
How to Cite
Boogaerts, I. I. F., Fortman, G. C., Furst, M. R. L., Cazin, C. S. J. and Nolan, S. P. (2010), Carboxylation of NH/CH Bonds Using N-Heterocyclic Carbene Copper(I) Complexes. Angew. Chem., 122: 8856–8859. doi: 10.1002/ange.201004153
- †
Publication History
- Issue published online: 4 NOV 2010
- Article first published online: 30 SEP 2010
- Manuscript Revised: 24 AUG 2010
- Manuscript Received: 7 JUL 2010
Funded by
- EPSRC
- ERC
Keywords:
- Carbenliganden;
- Carboxylierungen;
- C-H-Aktivierung;
- Kupferkatalyse;
- Stickstoffheterocyclen
Einfach und direkt verläuft die N-H- oder C-H-Funktionalisierung mit einem leicht zugänglichen Katalysator: [1,3-Bis(2,6-diisopropylphenyl)imidazol-2-yliden]kupfer(I)-hydroxid, [Cu(IPr)(OH)], aktiviert und carboxyliert N-H- und C-H-Bindungen mit pKS-Werten unter 27.7 (siehe Schema).