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Photochemical Activation of a Metal–Organic Framework to Reveal Functionality

Authors

  • Kristine K. Tanabe,

    1. Department of Chemistry and Biochemistry, University of California, San Diego, 9500 Gilman Drive, La Jolla, CA 92093 (USA), Fax: (+1) 858-822-5598
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  • Corinne A. Allen,

    1. Department of Chemistry and Biochemistry, University of California, San Diego, 9500 Gilman Drive, La Jolla, CA 92093 (USA), Fax: (+1) 858-822-5598
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  • Prof. Seth M. Cohen

    Corresponding author
    1. Department of Chemistry and Biochemistry, University of California, San Diego, 9500 Gilman Drive, La Jolla, CA 92093 (USA), Fax: (+1) 858-822-5598
    • Department of Chemistry and Biochemistry, University of California, San Diego, 9500 Gilman Drive, La Jolla, CA 92093 (USA), Fax: (+1) 858-822-5598
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  • C.A.A. and K.K.T. were equal contributors to this work. We thank Dr. M. Rouffet for synthesis of CAT-BDC, D. Martin for assistance with X-ray crystallography, and Dr. Y. Su for performing mass spectrometry experiments. We thank Prof. R. Snurr (Northwestern University) and Dr. Y.-S. Bae for BET calculations. This work was supported by UCSD, the NSF (new MOF synthesis CHE-0952370; instrumentation grants CHE-9709183, CHE-0116662 and CHE-0741968), and the DOE (gas sorption studies, PXRD, BES Grant No. DE- FG02-08ER46519).

Abstract

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„Blitzschnell“ zu neuen MOFs: In einer ungewöhnlichen postsynthetischen Entschützungsreaktion wurden zwei hochporöse Metall-organische Gerüste (MOFs) durch Bestrahlung mit UV-Licht in MOFs mit freien Hydroxy- und Catecholgruppen überführt (siehe Schema).

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