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Photodegradation of Target Oligosaccharides by Light-Activated Small Molecules

Authors

  • Dr. Daisuke Takahashi,

    1. Department of Applied Chemistry, Faculty of Science and Technology, Keio University, 3-14-1 Hiyoshi, Kohoku-ku, Yokohama 223-8522 (Japan), Fax: (+81) 45-566-1576
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  • Shingo Hirono,

    1. Department of Applied Chemistry, Faculty of Science and Technology, Keio University, 3-14-1 Hiyoshi, Kohoku-ku, Yokohama 223-8522 (Japan), Fax: (+81) 45-566-1576
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  • Chigusa Hayashi,

    1. Institute of Microbial Chemistry, 3-14-23 Kamiosaki, Shinagawa-ku, Tokyo 141-0021 (Japan)
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  • Dr. Masayuki Igarashi,

    1. Institute of Microbial Chemistry, 3-14-23 Kamiosaki, Shinagawa-ku, Tokyo 141-0021 (Japan)
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  • Dr. Yoshio Nishimura,

    1. Institute of Microbial Chemistry, 3-14-23 Kamiosaki, Shinagawa-ku, Tokyo 141-0021 (Japan)
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  • Prof. Dr. Kazunobu Toshima

    Corresponding author
    1. Department of Applied Chemistry, Faculty of Science and Technology, Keio University, 3-14-1 Hiyoshi, Kohoku-ku, Yokohama 223-8522 (Japan), Fax: (+81) 45-566-1576
    • Department of Applied Chemistry, Faculty of Science and Technology, Keio University, 3-14-1 Hiyoshi, Kohoku-ku, Yokohama 223-8522 (Japan), Fax: (+81) 45-566-1576
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  • This research was supported in part by High-Tech Research Center Project for Private Universities (Matching Fund Subsidy, 2006–2011) and by Grants-in-Aid for Young Scientists (B) (No. 22710220) and Scientific Research (B) (No. 20310140) from the Ministry of Education, Culture, Sports, Science and Technology of Japan (MEXT).

Abstract

original image

Leuchtend selektiv: Das maßgeschneiderte Anthrachinon-Boronsäure-Hybrid 1 bewirkt selektiv den Abbau von Oligosacchariden mit einem β-D-Galactofuranosidrest, die nur in den Zellwänden von Mykobakterien vorkommen. Der Abbau gelang mit langwelliger UV-Strahlung ohne Additive und unter neutralen Bedingungen.

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