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Zeotype Organic–Inorganic Ionic Crystals: Facile Cation Exchange and Controllable Sorption Properties

Authors

  • Dr. Sayaka Uchida,

    1. Department of Applied Chemistry, School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo (Japan), Fax: (+81) 3-5841-7220
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  • Ryo Eguchi,

    1. Department of Applied Chemistry, School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo (Japan), Fax: (+81) 3-5841-7220
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  • Prof. Dr. Noritaka Mizuno

    Corresponding author
    1. Department of Applied Chemistry, School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo (Japan), Fax: (+81) 3-5841-7220
    • Department of Applied Chemistry, School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo (Japan), Fax: (+81) 3-5841-7220
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  • This work was supported by the Core Research for Evolutional Science and Technology (CREST) program of the Japan Science and Technology Agency (JST), the Global COE Program (Chemistry Innovation through Cooperation of Science and Engineering), the Development in a New Interdisciplinary Field Based on Nanotechnology and Materials Science Programs, and Grant-in-Aid for Scientific Research from the Ministry of Education, Culture, Science, Sports, and Technology of Japan.

Abstract

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Kontrollierbare Sorption: Ein ionischer organisch-anorganischer Zeolithkristall mit 1D-Kanälen zeigt eine größenselektive Sorption: Die gastfreie Phase sorbiert Wasser und Methanol, während größere Moleküle ausgeschlossen bleiben. In den Kanälen befindliche K+-Ionen (siehe Bild; O rot, C schwarz, H lila, N blau) können gegen andere Alkalimetallionen ausgetauscht werden, und die Sorptionseigenschaften hängen von der Art des Alkalimetallions ab.

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