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Preparation of a Dihydrogen Complex of Cobalt†

  1. Dr. Travis J. Hebden1,
  2. Anthony J. St. John1,
  3. Prof. Dmitry G. Gusev2,
  4. Dr. Werner Kaminsky1,
  5. Prof. Karen I. Goldberg1,
  6. Prof.  D. Michael Heinekey1,*

Article first published online: 22 OCT 2010

DOI: 10.1002/ange.201005281

Issue

Angewandte Chemie

Angewandte Chemie

Volume 123, Issue 8, pages 1913–1916, February 18, 2011

Additional Information

How to Cite

Hebden, T. J., St. John, A. J., Gusev, D. G., Kaminsky, W., Goldberg, K. I. and Heinekey, D. M. (2011), Preparation of a Dihydrogen Complex of Cobalt. Angew. Chem., 123: 1913–1916. doi: 10.1002/ange.201005281

Author Information

  1. 1

    Department of Chemistry, University of Washington, Box 351700, Seattle, WA 98195 (USA), Fax: (+1) 206-685-8665

  2. 2

    Department of Chemistry, Wilfrid Laurier University, Waterloo, Ontario, N2L 3C5 (Canada)

*Department of Chemistry, University of Washington, Box 351700, Seattle, WA 98195 (USA), Fax: (+1) 206-685-8665

  1. †

    This work was made possible by the US National Science Foundation (CHE-0750503). Partial support was provided by the US DOE Center for Excellence in Chemical Hydrogen Storage and by the facilities of the Shared Hierarchical Academic Research Computing Network (SHARCNET:www.sharcnet.ca).

Publication History

  1. Issue published online: 16 FEB 2011
  2. Article first published online: 22 OCT 2010
  3. Manuscript Received: 24 AUG 2010

Funded by

  • US National Science Foundation. Grant Number: CHE-0750503

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Keywords:

  • Cobalt;
  • Dichtefunktionalrechnungen;
  • Dreizähnige Liganden;
  • Hydride;
  • Pinzettenliganden
Thumbnail image of graphical abstract

H2& Co.: Ein neuer Cobalt(II)-Pinzettenkomplex kann in Abwesenheit weiterer Liganden unter Bildung der hoch reaktiven Quecksilber-verbrückten Dicobaltspezies 1 reduziert werden. Nach der Behandlung mit H2 bei tiefer Temperatur gelingt es, den ungewöhnlichen Cobalt-Diwasserstoffkomplex 2 zu beobachten. Co blau, P gelb, O rot, Hg dunkelgrau.

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