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The Continuous-Flow Synthesis of Carboxylic Acids using CO2 in a Tube-In-Tube Gas Permeable Membrane Reactor

Authors

  • Dr. Anastasios Polyzos,

    1. Innovative Technology Centre, Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge, CB1 2EW (UK)
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  • Dr. Matthew O'Brien,

    1. Innovative Technology Centre, Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge, CB1 2EW (UK)
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  • Trine P. Petersen,

    1. Innovative Technology Centre, Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge, CB1 2EW (UK)
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  • Dr. Ian R. Baxendale,

    1. Innovative Technology Centre, Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge, CB1 2EW (UK)
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  • Prof. Steven V. Ley

    Corresponding author
    1. Innovative Technology Centre, Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge, CB1 2EW (UK)
    • Innovative Technology Centre, Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge, CB1 2EW (UK)
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  • We thank the following organizations for support and financial contributions to this project: Sanofi-Aventis, CSIRO Material Science and Engineering (A.P.), EPSRC (M.O.B.), the Danish Agency for Science, Technology and Innovation and H. Lundbeck A/S (T.P.P), the BP 1702 Chemistry Professorship (S.V.L.), and the Royal Society (I.R.B.).

Abstract

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Der einfache Weg: Das auf einer Doppelschlauchkonfiguration beruhende Titelsystem ermöglicht den sicheren, kontinuierlichen Gaseintrag in einen flüssigen Substratstrom und wurde für die Synthese von Carbonsäuren aus CO2 und Grignard-Reagentien genutzt (siehe Bild).

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