Helix-Sense-Selective Polymerization of Achiral Substituted Acetylenes in Chiral Micelles

Authors

  • Xiaofeng Luo,

    1. State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029 (China), Fax: (+86) 10-6443-5128
    2. College of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing 100029 (China)
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  • Prof. Jianping Deng,

    Corresponding author
    1. State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029 (China), Fax: (+86) 10-6443-5128
    2. College of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing 100029 (China)
    • State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029 (China), Fax: (+86) 10-6443-5128
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  • Prof. Wantai Yang

    1. State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029 (China), Fax: (+86) 10-6443-5128
    2. College of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing 100029 (China)
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  • This work was supported by the “Program for New Century Excellent Talents in University” (NCET-06-0096), the “National Science Foundation of China” (20974007), the “Scientific Research Foundation of Graduate School of Beijing University of Chemical and Technology” (09Ma002), the “Program for Changjiang Scholars and Innovative Research Team in University” (PCSIRT, IRT0706), and the “Major Project for Polymer Chemistry and Physics Subject Construction from Beijing Municipal Education Commission” (BMEC).

Abstract

original image

So bleibt man in Form: Ein achirales Acetylen geht in chiralen Micellen aus [{(nbd)RhCl}2] (nbd=2,5-Norbornadien) und Dodecylphenylalanin als chiralem Emulgator eine Helixsinn-selektive Polymerisation ein, bei der optisch aktive helicale Polymere und Polymeremulsionen gebildet werden.

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