Molecular Networks Based on Dative Boron–Nitrogen Bonds

Authors

  • Erin Sheepwash,

    1. Institut des Sciences et Ingénierie Chimiques, Ecole Polytechnique Fédérale de Lausanne (EPFL), 1015 Lausanne (Switzerland), Fax: (+41) 21-693-9305
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  • Vincent Krampl,

    1. Institut des Sciences et Ingénierie Chimiques, Ecole Polytechnique Fédérale de Lausanne (EPFL), 1015 Lausanne (Switzerland), Fax: (+41) 21-693-9305
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  • Dr. Rosario Scopelliti,

    1. Institut des Sciences et Ingénierie Chimiques, Ecole Polytechnique Fédérale de Lausanne (EPFL), 1015 Lausanne (Switzerland), Fax: (+41) 21-693-9305
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  • Olha Sereda,

    1. Centre Suisse d'Electronique et de Microtechnique (CSEM), 2002 Neuchâtel (Switzerland)
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  • Antonia Neels,

    1. Centre Suisse d'Electronique et de Microtechnique (CSEM), 2002 Neuchâtel (Switzerland)
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  • Prof. Kay Severin

    Corresponding author
    1. Institut des Sciences et Ingénierie Chimiques, Ecole Polytechnique Fédérale de Lausanne (EPFL), 1015 Lausanne (Switzerland), Fax: (+41) 21-693-9305
    • Institut des Sciences et Ingénierie Chimiques, Ecole Polytechnique Fédérale de Lausanne (EPFL), 1015 Lausanne (Switzerland), Fax: (+41) 21-693-9305
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  • This work was supported by funding from the Swiss National Science Foundation and by the EPFL. We thank Dr. Diego Carnevale (EPFL) for help with the solid-state 11B NMR measurements and Dr. Marco Cantoni and Fabienne Bobard (EPFL) for help with the SEM measurements.

Abstract

original image

Die BN-Verbindung: Kristalline und weiche molekulare Netzwerke lassen sich mithilfe dativer B-N-Bindungen aufbauen (siehe Bild). Sie entstehen in einer einstufigen Dreikomponentenreaktion zwischen einer Triboronsäure, einem Catechol und einem Bipyridyllinker.

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