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Comment on “A Low-Spin Ruthenium(IV)–Oxo Complex: Does the Spin State Have an Impact on the Reactivity”†

  1. Dr. Detlef Schröder1,*,
  2. Prof. Dr. Sason Shaik2,*

Article first published online: 25 MAR 2011

DOI: 10.1002/ange.201007636

Issue

Angewandte Chemie

Angewandte Chemie

Volume 123, Issue 17, pages 3934–3935, April 18, 2011

Additional Information

How to Cite

Schröder, D. and Shaik, S. (2011), Comment on “A Low-Spin Ruthenium(IV)–Oxo Complex: Does the Spin State Have an Impact on the Reactivity” . Angew. Chem., 123: 3934–3935. doi: 10.1002/ange.201007636

Author Information

  1. 1

    Institute of Organic Chemistry and Biochemistry, Academy of Sciences of the Czech Republic, Flemingovo náměstí 2, 16610 Prague 6 (Czech Republic), Fax: (+420) 2-2018-3462

  2. 2

    Department of Organic Chemistry, The Hebrew University, Givat Ram Campus, 91904 Jerusalem (Israel), Fax: (+972) 2-658-4680

*Institute of Organic Chemistry and Biochemistry, Academy of Sciences of the Czech Republic, Flemingovo náměstí 2, 16610 Prague 6 (Czech Republic), Fax: (+420) 2-2018-3462

  1. †

    This work was supported by the Czech Academy of Sciences (Z40550506), the European Research Council (AdG HORIZOMS), and the Lise-Meitner Minerva Center for Computational Quantum Chemistry. We thank Prof. Dr. F. Neese for helpful comments about the theoretical prediction of spin-state splittings.

Publication History

  1. Issue published online: 13 APR 2011
  2. Article first published online: 25 MAR 2011
  3. Manuscript Received: 6 DEC 2010

Funded by

  • Czech Academy of Sciences. Grant Number: Z40550506
  • European Research Council
  • Lise-Meitner Minerva Center for Computational Quantum Chemistry

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Keywords:

  • Elektronische Struktur;
  • Oxidationen;
  • Oxoliganden;
  • Reaktionsmechanismen;
  • Ruthenium

Wechselnde Spinzustände: Wenn für das Metallzentrum in einem Übergangsmetallkomplex mehrere Spinzustände möglich sind, kann das die Reaktivität des Komplexes beeinflussen. In solchen Fällen ist bei der Interpretation von experimentellen und theoretischen Befunden Vorsicht angebracht.

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